Organomet1996,_2845.pdf (137.19 kB)
Synthesis and theoretical studies of a diorganohydridoplatinum(IV) complex, PtHMe(2){(pz)(3)BH-N,N',N''}([(pz)(3)BH](-)=tris(pyrazol-1-yl)borate)
journal contribution
posted on 2023-05-16, 10:14 authored by Allan CantyAllan Canty, Dedieu, A, Jin, H, Milet, A, Richmond, MKThe platinum(II) tris(pyrazol-1-yl)borate complex [PtMe 2{(pz) 3BH-N1N′}] - reacts with phenol or aqueous HBF 4 in acetone to form the dimethylhydridoplatinum(IV) complex PtHMe 2{(pz) 3BH-N,N′,N″}. The complex decomposes above ∼140 °C in toluene-d 8 to give methane. Theoretical calculations at the SCF and MP2 levels for the species PtXMe 2{(H 2C=N-NH) 3BH-N,N′,N″} (where X = H, OH, Me and the fragment [(H 2C=-N-NH) 3BH] - is a model for [(pz) 3BH] -) yield geometries that compare well with structural reports for Pt(OH)-Me2{(pz) 3BH} and PdMe 3{(pz) 3BH}.
History
Publication title
OrganometallicsVolume
15Issue
12Pagination
2845-2847ISSN
0276-7333Department/School
School of Natural SciencesPublisher
Amer Chemical SocPlace of publication
United States of AmericaRepository Status
- Restricted