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First Cr(III)-SNS Complexes and Their Use as Highly Efficient Catalysts for the Trimerization of Ethylene to 1-Hexene
journal contribution
posted on 2023-05-16, 19:50 authored by McGuinness, DS, Wasserscheid, P, Keim, W, Morgan, D, Dixon, JT, Bollmann, A, Maumela, H, Hess, F, Englert, UCr(III) complexes of tridentate SNS ligands have been prepared and evaluated as catalysts for ethylene trimerization, with several giving very high activity and excellent selectivity toward 1-hexene when activated with methylaluminoxane. The new complexes illustrate the potential of sulfur-based ligands on early transition metals for catalysis. Copyright © 2003 American Chemical Society.
History
Publication title
Journal of the American Chemical SocietyVolume
125Issue
18Pagination
5272-5273ISSN
0002-7863Department/School
School of Natural SciencesPublisher
American Chemical SocietyPlace of publication
WashingtonRepository Status
- Restricted