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Bis[tris(pyridin-2-yl)methanol-kappa 2N,N ']palladium(II) dinitrate at 150 and 298 K


Canty, AJ and Skelton, BW and Traill, PR and White, AH, Bis[tris(pyridin-2-yl)methanol-kappa 2N,N ']palladium(II) dinitrate at 150 and 298 K, Acta Crystallographica Section C - Crystal Structure Communications, 60, (7) pp. m305-m307. ISSN 0108-2701 (2004) [Refereed Article]

DOI: doi:10.1107/S0108270104010893


The title complex, [Pd{(py)3COH}2](NO 3)2, where (py)3COH is tris(pyridin-2-yl) methanol (C16H13N3O), studied at 150 and 298 K, has the potentially tridentate ligands present as bidentate ligands, with the Pd atom at a centre of symmetry. At 150 K, the Pd - N distances are 2.022 (3) and 2.026 (3) Å. The mean planes of the coordinated pyridine groups form dihedral angles of 42.1 (1) and 45.3 (1)° (at 150 K) with the coordination plane; the uncoordinated rings situated either side of the coordination plane form dihedral angles of 42.2 (1)° with it. The nitrate ions are regular and interact weakly with the hydroxyl group.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Inorganic chemistry
Research Field:Transition metal chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding knowledge
Objective Field:Expanding knowledge in the chemical sciences
UTAS Author:Canty, AJ (Professor Allan Canty)
UTAS Author:Traill, PR (Mr Peter Traill)
ID Code:31953
Year Published:2004
Web of Science® Times Cited:2
Deposited By:Chemistry
Deposited On:2004-08-01
Last Modified:2011-09-19

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