AC2C_C602C_m305.pdf (266.24 kB)
Bis[tris(pyridin-2-yl)methanol-kappa 2N,N ']palladium(II) dinitrate at 150 and 298 K
journal contribution
posted on 2023-05-16, 15:37 authored by Allan CantyAllan Canty, Skelton, BW, Traill, PR, White, AHThe title complex, [Pd{(py)3COH}2](NO 3)2, where (py)3COH is tris(pyridin-2-yl) methanol (C16H13N3O), studied at 150 and 298 K, has the potentially tridentate ligands present as bidentate ligands, with the Pd atom at a centre of symmetry. At 150 K, the Pd - N distances are 2.022 (3) and 2.026 (3) Å. The mean planes of the coordinated pyridine groups form dihedral angles of 42.1 (1) and 45.3 (1)° (at 150 K) with the coordination plane; the uncoordinated rings situated either side of the coordination plane form dihedral angles of 42.2 (1)° with it. The nitrate ions are regular and interact weakly with the hydroxyl group.
History
Publication title
Acta Crystallographica Section C - Crystal Structure CommunicationsVolume
60Issue
7Pagination
m305-m307ISSN
0108-2701Department/School
School of Natural SciencesPublisher
Blackwell MunksgaardPlace of publication
CopenhagenRepository Status
- Restricted