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Bis[tris(pyridin-2-yl)methanol-kappa 2N,N ']palladium(II) dinitrate at 150 and 298 K

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posted on 2023-05-16, 15:37 authored by Allan CantyAllan Canty, Skelton, BW, Traill, PR, White, AH
The title complex, [Pd{(py)3COH}2](NO 3)2, where (py)3COH is tris(pyridin-2-yl) methanol (C16H13N3O), studied at 150 and 298 K, has the potentially tridentate ligands present as bidentate ligands, with the Pd atom at a centre of symmetry. At 150 K, the Pd - N distances are 2.022 (3) and 2.026 (3) Å. The mean planes of the coordinated pyridine groups form dihedral angles of 42.1 (1) and 45.3 (1)° (at 150 K) with the coordination plane; the uncoordinated rings situated either side of the coordination plane form dihedral angles of 42.2 (1)° with it. The nitrate ions are regular and interact weakly with the hydroxyl group.

History

Publication title

Acta Crystallographica Section C - Crystal Structure Communications

Volume

60

Issue

7

Pagination

m305-m307

ISSN

0108-2701

Department/School

School of Natural Sciences

Publisher

Blackwell Munksgaard

Place of publication

Copenhagen

Repository Status

  • Restricted

Socio-economic Objectives

Expanding knowledge in the chemical sciences

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