AC_2C_C60_2C_o98.pdf (224.75 kB)
1-Bromo-2,6-bis[(pyrazol-1-yl)methyl]benzene
journal contribution
posted on 2023-05-16, 15:37 authored by Allan CantyAllan Canty, Honeyman, RT, Skelton, BW, White, AHThe crystal structure and oxidative addition reaction of 1-bromo-2,6-bis[(pyrazol-1-yl)-methyl]benzene were discussed. It was observed that the pendant pyrazole rings formed dihedral angles of 83.8(3) and 89.3(3)° with the central planar unit of the compound. It was found that a platinum complex with the [N-C-N] group was formed during the oxidative addition reaction of 1-bromo-2,6-bis[(pyrazol-1-yl)-methyl]benzene with [PtMe2(SEt2). Results show that the assymetric unit comprised of a single molecule and the planes of peripheral pyrazole were quasi-normal to the central ring.
History
Publication title
Acta Crystallographica Section C - Crystal Structure CommunicationsVolume
60Pagination
o98-o99ISSN
0108-2701Department/School
School of Natural SciencesPublisher
Blackwell MunksgaardPlace of publication
CopenhagenRepository Status
- Restricted