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1-Bromo-2,6-bis[(pyrazol-1-yl)methyl]benzene

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posted on 2023-05-16, 15:37 authored by Allan CantyAllan Canty, Honeyman, RT, Skelton, BW, White, AH
The crystal structure and oxidative addition reaction of 1-bromo-2,6-bis[(pyrazol-1-yl)-methyl]benzene were discussed. It was observed that the pendant pyrazole rings formed dihedral angles of 83.8(3) and 89.3(3)° with the central planar unit of the compound. It was found that a platinum complex with the [N-C-N] group was formed during the oxidative addition reaction of 1-bromo-2,6-bis[(pyrazol-1-yl)-methyl]benzene with [PtMe2(SEt2). Results show that the assymetric unit comprised of a single molecule and the planes of peripheral pyrazole were quasi-normal to the central ring.

History

Publication title

Acta Crystallographica Section C - Crystal Structure Communications

Volume

60

Pagination

o98-o99

ISSN

0108-2701

Department/School

School of Natural Sciences

Publisher

Blackwell Munksgaard

Place of publication

Copenhagen

Repository Status

  • Restricted

Socio-economic Objectives

Expanding knowledge in the chemical sciences

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