JOMC1998,_552.pdf (198.12 kB)
Synthesis and reactivity of poly(pyrazol-1-yl)borate derivatives of cyclopalladation systems, including structural studies of Pd{2-CH2C6H4P(o-tolyl)(2)-C,P}{(pz)(3)BH-N,N '} and Pd(C6H4C5H4N-C-2,N '){(pz)(3)BH-N,N '}
journal contribution
posted on 2023-05-16, 11:14 authored by Allan CantyAllan Canty, Hoare, JL, Skelton, BW, White, AH, van Koten, GThe cyclopalladated complexes Pd{2-CH2C6H4P(o-tol)2}{(pz) nBH4-n} and Pd(C6H4C5H4N-C 2,N′){(pz)nBH4-n} [n=2, 3; pz=pyrazol-1-yl] have been synthesised from the corresponding halide bridged cyclometallated dimers; the crystal structures of the complexes for which n=3 have been determined. The complexes Pd{2-CH2C6H4P(o-tol)2}{(pz) nBH4-n} (n=2, 3) and [Pd{2-CH2C6H4P(o-tol)2}(μ-O 2CMe)]2 are unreactive towards oxidation by alkyl halides, iodobenzene and 4-bromoanisole.
History
Publication title
Journal of Organometallic ChemistryVolume
552Issue
1-2Pagination
23-29ISSN
0022-328XDepartment/School
School of Natural SciencesPublisher
ElsevierPlace of publication
The NetherlandsRepository Status
- Restricted