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Aryl–Fluoride Bond-Forming Reductive Elimination from Nickel(IV) Centers
journal contribution
posted on 2023-05-20, 06:50 authored by Meucci, EA, Alireza AriafardAlireza Ariafard, Allan CantyAllan Canty, Kampf, JW, Sanford, MSThe treatment of pyridine- and pyrazole-ligated NiII σ-aryl complexes with Selectfluor results in C(sp2)–F bond formation under mild conditions. With appropriate design of supporting ligands, diamagnetic NiIV σ-aryl fluoride intermediates can be detected spectroscopically and/or isolated during these transformations. These studies demonstrate for the first time that NiIV σ-aryl fluoride complexes participate in challenging C(sp2)–F bond-forming reductive elimination to yield aryl fluoride products.
History
Publication title
Journal of the American Chemical SocietyVolume
141Issue
33Pagination
13261-13267ISSN
0002-7863Department/School
School of Natural SciencesPublisher
American Chemical SocietyPlace of publication
Washington, USARights statement
Copyright © 2019 American Chemical SocietyRepository Status
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