(2',2'-Bipyridyl-N,N)_dibromopalladuim.pdf (139.25 kB)
(2,2'-bipyridyl-N,N')dibromopalladium(II)
journal contribution
posted on 2023-05-16, 10:52 authored by Smeets, WJJ, Spek, AL, Hoare, JL, Allan CantyAllan Canty, Hovestad, N, Van Koten, GThe title complex, [PdBr2(C10H8N2)], has square-planar geometry for palladium with Pd - N 2.047 (5) and Pd - Br 2.4102 (9) Å. The mean planes of the coordinated pyridine groups form a dihedral angle of 1.7(3)○ with the coordination square plane; the parallel complexes stack with an interplanar spacing of 3.41 (1) Å and a PP ⋯Pd separation of 5.246 (1) Å to form a chain structure as reported for isomorphous PtI2(bipy) (where bipy is 2,2′-bipyridyl, C10H8N2). The structure differs from those found for related chain structures in the 'red' form of PtCl2(bipy) and in PdCl2(bipy) which is isomorphous with the 'yellow' form of PtCl2(bipy).
History
Publication title
Acta Crystallographica. Section C: Crystal Structure CommunicationsVolume
53Issue
8Pagination
1045-1047ISSN
0108-2701Department/School
School of Natural SciencesPublisher
International Union of CrystallographyPlace of publication
DenmarkRepository Status
- Restricted