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Carbon-Carbon Bond-Forming Reductive Elimination from Isolated Nickel(III) Complexes
journal contribution
posted on 2023-05-19, 02:21 authored by Bour, JR, Camasso, NM, Meucci, EA, Kampf, JW, Allan CantyAllan Canty, Sanford, MSThis manuscript describes the design, synthesis, characterization, and reactivity studies of organometallic NiIII complexes of general structure TpNiIII(R)(R1) (Tp = tris(pyrazolyl)borate). With appropriate selection of the R and R1 ligands, the complexes are stable at room temperature and can be characterized by cyclic voltammetry, EPR spectroscopy, and X-ray crystallography. Upon heating, many of these NiIII compounds undergo C(sp2)–C(sp2) or C(sp3)–C(sp2) bond-forming reactions that are challenging at lower oxidation states of nickel.
History
Publication title
Journal of the American Chemical SocietyVolume
138Issue
49Pagination
16105-16111ISSN
0002-7863Department/School
School of Natural SciencesPublisher
American Chemical SocietyPlace of publication
United StatesRights statement
Copyright 2016 American Chemical SocietyRepository Status
- Restricted