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Synthesis of polystyrene nanoparticles 'armoured' with nanodimensional graphene oxide sheets by miniemulsion polymerization


Che Man, SH and Thickett, SC and Whittaker, MR and Zetterlund, PB, Synthesis of polystyrene nanoparticles 'armoured' with nanodimensional graphene oxide sheets by miniemulsion polymerization, Journal of Polymer Science Part A: Polymer Chemistry, 51, (1) pp. 47-58. ISSN 0887-624X (2013) [Refereed Article]

Copyright Statement

Copyright 2012 Wiley Periodicals, Inc.

DOI: doi:10.1002/pola.26341


Polystyrene particles "armoured" with nanosized graphene oxide (GO) sheets have been prepared by aqueous miniemulsion polymerization of styrene, exploiting the amphiphilic properties of GO in the absence of conventional surfactants. The nanoscale GO sheets were prepared from graphite nanofibers of diameter approximately 100 nm based on a novel procedure, thus effectively ensuring the absence of larger sheets. Polymerization proceeded to high conversion with minor coagulation, with final number-average particle diameters of approximately 500 nm, but relatively broad particle size distributions. Scanning electron microscopy analysis revealed particles with a textured surface, consistent with the expected morphology. Interestingly, analysis of GO sheets recovered from the polymerization revealed that the GO sheets are partially reduced during the polymerization—approximately 50% of the initial carboxyl groups of the GO were lost, consistent with some loss in colloidal stability at high conversion. The overall approach offers a convenient and attractive synthetic route to novel graphene-based polymeric nanostructures.

Item Details

Item Type:Refereed Article
Keywords:nanocomposites, nanoparticles, polystyrene, radical polymerization
Research Division:Engineering
Research Group:Materials engineering
Research Field:Composite and hybrid materials
Objective Division:Expanding Knowledge
Objective Group:Expanding knowledge
Objective Field:Expanding knowledge in the chemical sciences
UTAS Author:Thickett, SC (Associate Professor Stuart Thickett)
ID Code:99393
Year Published:2013
Web of Science® Times Cited:55
Deposited By:Chemistry
Deposited On:2015-03-23
Last Modified:2017-10-24

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