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On the selective cleavage of nitrous oxide by metal-amide complexes

journal contribution
posted on 2023-05-18, 07:42 authored by Cavigliasso, G, Criddle, A, Kim, H-S, Stranger, R, Brian YatesBrian Yates
Computational investigation of nitrous oxide cleavage by metal– amide systems has shown that a bimetallic mechanism is compatible with the remarkable experimental observation of selective N–N bond scission by a di-molybdenum system, and that the interplay between the bonding energetics of reactants and products can both provide an explanation for the observed cleavage selectivity and be utilized to modify and design chemical behaviour.

History

Publication title

Dalton Transactions

Volume

43

Issue

12

Pagination

4631-4634

ISSN

1477-9226

Department/School

School of Natural Sciences

Publisher

Royal Soc Chemistry

Place of publication

Thomas Graham House, Science Park, Milton Rd, Cambridge, England, Cambs, Cb4 0Wf

Rights statement

Copyright 2014 The Royal Society of Chemistry

Repository Status

  • Restricted

Socio-economic Objectives

Expanding knowledge in the chemical sciences

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