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On the selective cleavage of nitrous oxide by metal-amide complexes
journal contribution
posted on 2023-05-18, 07:42 authored by Cavigliasso, G, Criddle, A, Kim, H-S, Stranger, R, Brian YatesBrian YatesComputational investigation of nitrous oxide cleavage by metal– amide systems has shown that a bimetallic mechanism is compatible with the remarkable experimental observation of selective N–N bond scission by a di-molybdenum system, and that the interplay between the bonding energetics of reactants and products can both provide an explanation for the observed cleavage selectivity and be utilized to modify and design chemical behaviour.
History
Publication title
Dalton TransactionsVolume
43Issue
12Pagination
4631-4634ISSN
1477-9226Department/School
School of Natural SciencesPublisher
Royal Soc ChemistryPlace of publication
Thomas Graham House, Science Park, Milton Rd, Cambridge, England, Cambs, Cb4 0WfRights statement
Copyright 2014 The Royal Society of ChemistryRepository Status
- Restricted