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On the selective cleavage of nitrous oxide by metal-amide complexes
Citation
Cavigliasso, G and Criddle, A and Kim, H-S and Stranger, R and Yates, BF, On the selective cleavage of nitrous oxide by metal-amide complexes, Dalton Transactions, 43, (12) pp. 4631-4634. ISSN 1477-9226 (2014) [Refereed Article]
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Copyright Statement
Copyright 2014 The Royal Society of Chemistry
Abstract
Computational investigation of nitrous oxide cleavage by metal–
amide systems has shown that a bimetallic mechanism is compatible
with the remarkable experimental observation of selective N–N
bond scission by a di-molybdenum system, and that the interplay
between the bonding energetics of reactants and products can
both provide an explanation for the observed cleavage selectivity
and be utilized to modify and design chemical behaviour.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Other Chemical Sciences |
| Research Field: | Organometallic Chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding Knowledge |
| Objective Field: | Expanding Knowledge in the Chemical Sciences |
| Author: | Yates, BF (Professor Brian Yates) |
| ID Code: | 98587 |
| Year Published: | 2014 |
| Web of Science® Times Cited: | 4 |
| Deposited By: | Chemistry |
| Deposited On: | 2015-02-19 |
| Last Modified: | 2018-03-14 |
| Downloads: | 0 |
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