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On the selective cleavage of nitrous oxide by metal-amide complexes

Citation

Cavigliasso, G and Criddle, A and Kim, H-S and Stranger, R and Yates, BF, On the selective cleavage of nitrous oxide by metal-amide complexes, Dalton Transactions, 43, (12) pp. 4631-4634. ISSN 1477-9226 (2014) [Refereed Article]


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Copyright Statement

Copyright 2014 The Royal Society of Chemistry

DOI: doi:10.1039/c3dt53062k

Abstract

Computational investigation of nitrous oxide cleavage by metal– amide systems has shown that a bimetallic mechanism is compatible with the remarkable experimental observation of selective N–N bond scission by a di-molybdenum system, and that the interplay between the bonding energetics of reactants and products can both provide an explanation for the observed cleavage selectivity and be utilized to modify and design chemical behaviour.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Other Chemical Sciences
Research Field:Organometallic Chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Yates, BF (Professor Brian Yates)
ID Code:98587
Year Published:2014
Web of Science® Times Cited:4
Deposited By:Chemistry
Deposited On:2015-02-19
Last Modified:2015-08-06
Downloads:0

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