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Analysis of the enol–keto tautomers of indole-3-pyruvic acid
Citation
Tivendale, ND and Davies, NW and Horne, J and Ross, JJ and Smith, JA, Analysis of the enol-keto tautomers of indole-3-pyruvic acid, Australian Journal of Chemistry, 68, (2) pp. 345-348. ISSN 0004-9425 (2015) [Refereed Article]
Copyright Statement
Copyright 2015 CSIRO
DOI: doi:10.1071/CH14343
Abstract
Indole-3-pyruvic acid (IPyA) is an important naturally occurring biosynthetic intermediate whose quantitation by standard
analytic techniques can be complicated as it can exist as either the keto or enol tautomer. Here, we present a detailed
analysis of the tautomerism of IPyA and provide further evidence that the two tautomers of IPyA may be readily separated
by ultra high-performance liquid chromatography and that the relative proportions of each form may be controlled using
temperature and pH.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Keywords: | indole-3-pyruvic acid, emol-keto tautomer, IAA |
| Research Division: | Biological Sciences |
| Research Group: | Plant Biology |
| Research Field: | Plant Physiology |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding Knowledge |
| Objective Field: | Expanding Knowledge in the Biological Sciences |
| UTAS Author: | Tivendale, ND (Mr Nathan Tivendale) |
| UTAS Author: | Davies, NW (Associate Professor Noel Davies) |
| UTAS Author: | Horne, J (Mr John Horne) |
| UTAS Author: | Ross, JJ (Associate Professor John Ross) |
| UTAS Author: | Smith, JA (Associate Professor Jason Smith) |
| ID Code: | 98131 |
| Year Published: | 2015 (online first 2014) |
| Web of Science® Times Cited: | 1 |
| Deposited By: | Plant Science |
| Deposited On: | 2015-02-03 |
| Last Modified: | 2017-10-25 |
| Downloads: | 0 |
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