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Concentration measurements and isotopic composition of airborne molybdenum collected in an urban environment

Citation

Lane, S and Proemse, BC and Tennant, A and Wieser, ME, Concentration measurements and isotopic composition of airborne molybdenum collected in an urban environment, Analytical and Bioanalytical Chemistry, 405, (9) pp. 2957-2963. ISSN 1618-2642 (2013) [Refereed Article]

Copyright Statement

Copyright 2013 Springer

DOI: doi:10.1007/s00216-012-6660-9

Abstract

Here, we report the first measurements of the molybdenum (Mo) isotopic composition of aerosols collected on Teflon air filters. Mo concentrations and isotopic compositions were measured at selected locations in the city of Calgary, Canada, including a residence, the isotope laboratory at the University of Calgary, the University of Calgary weather station, and the City of Calgary Transit bus garage. Concentrations ranged from 0.07 ng/m3 in the laboratory to 19.0 ng/m3 in the bus garage. The concentrations of Mo in the air samples collected in the bus garage were the highest measured in this study. To date, there are no reported data for the Mo isotopic composition of airborne Mo. In this study, the δ98/95Mo values measured for the different urban sampling sites and reported relative to SRM 3134, ranged from −0.18 to +0.94 ‰. The results of this investigation suggest that measurements of Mo concentrations and isotopic compositions have the potential to trace anthropogenic emissions in an urban environment.

Item Details

Item Type:Refereed Article
Keywords:molybdenum, isotopes, air quality, urban, vehicle emissions
Research Division:Environmental Sciences
Research Group:Environmental Science and Management
Research Field:Environmental Monitoring
Objective Division:Environment
Objective Group:Air Quality
Objective Field:Urban and Industrial Air Quality
Author:Proemse, BC (Dr Bernadette Proemse)
ID Code:98038
Year Published:2013
Web of Science® Times Cited:7
Deposited By:Zoology
Deposited On:2015-01-29
Last Modified:2015-02-03
Downloads:0

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