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Formation of ethane from mono-methyl palladium(II) complexes

journal contribution
posted on 2023-05-18, 05:41 authored by Lotz, MD, Remy, MS, Lao, DB, Alireza AriafardAlireza Ariafard, Brian YatesBrian Yates, Allan CantyAllan Canty, Mayer, JM, Sanford, MS
This article describes the high-yielding and selective oxidatively induced formation of ethane from mono-methyl palladium complexes. Mechanistic details of this reaction have been explored via both experiment and computation. On the basis of these studies, a mechanism involving methyl group transmetalation between PdII and PdIV interediates is proposed.

History

Publication title

Journal of the American Chemical Society

Volume

136

Issue

23

Pagination

8237-8242

ISSN

0002-7863

Department/School

School of Natural Sciences

Publisher

Amer Chemical Soc

Place of publication

1155 16Th St, Nw, Washington, USA, Dc, 20036

Rights statement

Copyright 2014 American Chemical Society

Repository Status

  • Restricted

Socio-economic Objectives

Expanding knowledge in the chemical sciences

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