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Formation of ethane from mono-methyl palladium(II) complexes
journal contribution
posted on 2023-05-18, 05:41 authored by Lotz, MD, Remy, MS, Lao, DB, Alireza AriafardAlireza Ariafard, Brian YatesBrian Yates, Allan CantyAllan Canty, Mayer, JM, Sanford, MSThis article describes the high-yielding and selective oxidatively induced formation of ethane from mono-methyl palladium complexes. Mechanistic details of this reaction have been explored via both experiment and computation. On the basis of these studies, a mechanism involving methyl group transmetalation between PdII and PdIV interediates is proposed.
History
Publication title
Journal of the American Chemical SocietyVolume
136Issue
23Pagination
8237-8242ISSN
0002-7863Department/School
School of Natural SciencesPublisher
Amer Chemical SocPlace of publication
1155 16Th St, Nw, Washington, USA, Dc, 20036Rights statement
Copyright 2014 American Chemical SocietyRepository Status
- Restricted