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Porous layer open tubular monolith capillary column: switching-off the reaction kinetics as the governing factor in their preparation by using an immiscible liquid-controlled polymerization

Citation

Knob, R and Breadmore, MC and Guijt, RM and Petr, J and Macka, M, Porous layer open tubular monolith capillary column: switching-off the reaction kinetics as the governing factor in their preparation by using an immiscible liquid-controlled polymerization, RSC Advances: an international journal to further the chemical sciences, 3, (47) pp. 24927-24930. ISSN 2046-2069 (2013) [Refereed Article]

Copyright Statement

Copyright 2013 The Royal Society of Chemistry

DOI: doi:10.1039/c2ra23417c

Abstract

A new approach for preparation of monolithic porous layer opentubular capillary columns that eliminates the need for incomplete polymerization is presented. By expelling monomers from the capillary with a completely immiscible liquid a thin layer of polymerization mixture that wets the wall is left and polymerized by UV light.

Item Details

Item Type:Refereed Article
Keywords:monolith, porous layer, open tubular capillary column, reaction kinetics, photopolymerisation, LED
Research Division:Chemical Sciences
Research Group:Analytical Chemistry
Research Field:Separation Science
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Knob, R (Mr Radim Knob)
Author:Breadmore, MC (Professor Michael Breadmore)
Author:Guijt, RM (Dr Rosanne Guijt)
Author:Macka, M (Professor Mirek Macka)
ID Code:89316
Year Published:2013
Funding Support:Australian Research Council (FT120100559)
Web of Science® Times Cited:4
Deposited By:Chemistry
Deposited On:2014-02-28
Last Modified:2014-06-23
Downloads:0

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