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Microwave-assisted synthesis of 5-arylbenzofuran-2-carboxylates via Suzuki coupling using a 2-quinolinealdoxime-Pd(II)-complex


Dawood, KM and Farag, AM and El-Deftar, MM and Gardiner, M and Abdelaziz, HA, Microwave-assisted synthesis of 5-arylbenzofuran-2-carboxylates via Suzuki coupling using a 2-quinolinealdoxime-Pd(II)-complex, Arkivoc, 2013, (3) pp. 210-226. ISSN 1551-7012 (2013) [Refereed Article]


Copyright Statement

Copyright 2013 ARKAT-USA Licensed under Creative Commons Attribution-NonCommercial 3.0 Unported (CC BY-NC 3.0

DOI: doi:10.3998/ark.5550190.0014.317


A new quinoline-based Pd(II)-complex was synthesized and its structure was established by single crystal X-ray analysis. Applications of the obtained complex as a precatalyst in Suzuki-Miyaura C-C cross-coupling reactions of 4-bromoacetophenone and 5-bromobenzofuran-2-carboxylate esters with several aryl- and heteroarylboronic acids were investigated. The catalytic activity of the Pd(II)-precatalyst under microwave irradiating conditions was evaluated. © ARKAT-USA, Inc.

Item Details

Item Type:Refereed Article
Keywords:catalysis, organometallic, palladium, quinolines, benzofurans, palladium catalysis, microwave, Suzuki reactions
Research Division:Chemical Sciences
Research Group:Inorganic chemistry
Research Field:Transition metal chemistry
Objective Division:Manufacturing
Objective Group:Industrial chemicals and related products
Objective Field:Inorganic industrial chemicals
UTAS Author:Gardiner, M (Associate Professor Michael Gardiner)
ID Code:89110
Year Published:2013
Web of Science® Times Cited:12
Deposited By:Chemistry
Deposited On:2014-02-25
Last Modified:2017-10-25
Downloads:549 View Download Statistics

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