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Cu-catalyzed fluorination of diaryliodonium salts with KF
Citation
Ichiishi, N and Canty, AJ and Yates, BF and Sanford, MS, Cu-catalyzed fluorination of diaryliodonium salts with KF, Organic Letters, 15, (19) pp. 5134-5137. ISSN 1523-7060 (2013) [Refereed Article]
Copyright Statement
Copyright 2013 American Chemical Society
Abstract
A mild Cu-catalyzed nucleophilic fluorination of unsymmetrical diaryliodonium salts with KF is described. This protocol preferentially fluorinates the smaller aromatic ligand on iodine(III). The reaction exhibits a broad substrate scope and proceeds with high chemoselectivity and functional group tolerance. DFT calculations implicate a CuI/CuIII catalytic cycle.
Item Details
Item Type: | Refereed Article |
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Research Division: | Chemical Sciences |
Research Group: | Organic chemistry |
Research Field: | Organic chemical synthesis |
Objective Division: | Expanding Knowledge |
Objective Group: | Expanding knowledge |
Objective Field: | Expanding knowledge in the chemical sciences |
UTAS Author: | Canty, AJ (Professor Allan Canty) |
UTAS Author: | Yates, BF (Professor Brian Yates) |
ID Code: | 88261 |
Year Published: | 2013 |
Web of Science® Times Cited: | 125 |
Deposited By: | Chemistry |
Deposited On: | 2014-01-23 |
Last Modified: | 2017-10-25 |
Downloads: | 0 |
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