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Cu-catalyzed fluorination of diaryliodonium salts with KF
Citation
Ichiishi, N and Canty, AJ and Yates, BF and Sanford, MS, Cu-catalyzed fluorination of diaryliodonium salts with KF, Organic Letters, 15, (19) pp. 5134-5137. ISSN 1523-7060 (2013) [Refereed Article]
Copyright Statement
Copyright 2013 American Chemical Society
Abstract
A mild Cu-catalyzed nucleophilic fluorination of unsymmetrical diaryliodonium salts with KF is described. This protocol preferentially fluorinates the smaller aromatic ligand on iodine(III). The reaction exhibits a broad substrate scope and proceeds with high chemoselectivity and functional group tolerance. DFT calculations implicate a CuI/CuIII catalytic cycle.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Organic Chemistry |
| Research Field: | Organic Chemical Synthesis |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding Knowledge |
| Objective Field: | Expanding Knowledge in the Chemical Sciences |
| Author: | Canty, AJ (Professor Allan Canty) |
| Author: | Yates, BF (Professor Brian Yates) |
| ID Code: | 88261 |
| Year Published: | 2013 |
| Web of Science® Times Cited: | 76 |
| Deposited By: | Chemistry |
| Deposited On: | 2014-01-23 |
| Last Modified: | 2014-06-17 |
| Downloads: | 0 |
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