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Trace element heterogeneity in molybdenite fingerprints stages of mineralization

Citation

Ciobanu, CL and Cook, NJ and Kelson, CR and Guerin, R and Kalleske, N and Danyushevsky, L, Trace element heterogeneity in molybdenite fingerprints stages of mineralization, Chemical Geology, 347 pp. 175-189. ISSN 0009-2541 (2013) [Refereed Article]

Copyright Statement

Copyright 2013 Elsevier B.V.

DOI: doi:10.1016/j.chemgeo.2013.03.011

Abstract

Variations in molybdenite trace element chemistry represent a tool for discriminating discrete events in young magmatic-hydrothermal systems and constrain the role of granites in older greenstone belt-hosted gold systems. We show that besides Re and W (typical lattice-bound elements), molybdenite also concentrates chalcophile elements with chalcogenide affinity such as Bi, Pb, and Te (CEs). Elements from the latter group form nano- to micron-scale inclusions which also attract Au and Ag incorporation. High concentration of all elements is attributable to lattice-defects and coherent intergrowths between molybdenite and CE-minerals rather than polytypism. If both groups are used, trace element patterns are useful for interpreting superimposed ore-forming processes. We test the validity of this hypothesis by carrying out Laser-Ablation Inductively-Coupled Mass Spectroscopy spot analysis and element mapping on high-Re molybdenite from the Tertiary Au deposit at Hilltop (NV, USA) and the Archean Boddington Cu-Au deposit (Western Australia). Whereas W and CEs are affected by both deformation and interaction with subsequent fluids, Re is only affected by the latter. An epithermal overprint at Hilltop, recorded in a grain with a CE-rich halo surrounding a core with Re-W oscillatory zoning, upgrades Re content and is also traceable by measurable Au. At Boddington, granite-derived fluids dilute Re in precursor molybdenite, but both granite and orogenic deformation assist CE-mineral coarsening and Au release.

Item Details

Item Type:Refereed Article
Keywords:Molybdenite Laser-Ablation Inductively-Coupled Mass Spectroscopy Element mapping Bismuth Gold
Research Division:Earth Sciences
Research Group:Geology
Research Field:Ore Deposit Petrology
Objective Division:Mineral Resources (excl. Energy Resources)
Objective Group:Mineral Exploration
Objective Field:Mineral Exploration not elsewhere classified
Author:Danyushevsky, L (Professor Leonid Danyushevsky)
ID Code:87885
Year Published:2013
Deposited By:Centre for Ore Deposit Research - CODES CoE
Deposited On:2013-12-14
Last Modified:2014-05-23
Downloads:0

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