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Optimization of the response of phosphate separated by capillary zone electrophoresis
Citation
Harakuwe, AH and Haddad, PR, Optimization of the response of phosphate separated by capillary zone electrophoresis, Analytical Communications, 33, (3) pp. 103-105. ISSN 1359-7337 (1996) [Refereed Article]
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Copyright Statement
Copyright © 1996 Royal Society of Chemistry
Official URL: http://www.rsc.org
Abstract
The response of phosphate, which is highly variable in capillary zone electrophoresis (CZE) using silica capillaries, was optimized by monitoring the absorption of phosphate onto the capillary surface. A capillary conditioning regime is described which facilitates maximum response for phosphate without significantly extending the total analysis time. The described regime also allowed excellent precision (?0.36%sr, n= 10) to be achieved with regard to absolute migration time for phosphate as well as chloride, bromide, sulfate and hydrogencarbonate. Using this regime, the precisions for the phosphate peak area and height were 9 and 5.5%sr, respectively (n= 10).
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Analytical chemistry |
| Research Field: | Instrumental methods (excl. immunological and bioassay methods) |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding knowledge |
| Objective Field: | Expanding knowledge in the chemical sciences |
| UTAS Author: | Harakuwe, AH (Mr Anthony Hekare Harakuwe) |
| UTAS Author: | Haddad, PR (Professor Paul Haddad) |
| ID Code: | 8657 |
| Year Published: | 1996 |
| Web of Science® Times Cited: | 7 |
| Deposited By: | Chemistry |
| Deposited On: | 1996-08-01 |
| Last Modified: | 2010-03-14 |
| Downloads: | 0 |
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