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Optimization of the response of phosphate separated by capillary zone electrophoresis

Citation

Harakuwe, AH and Haddad, PR, Optimization of the response of phosphate separated by capillary zone electrophoresis, Analytical Communications, 33, (3) pp. 103-105. ISSN 1359-7337 (1996) [Refereed Article]


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Copyright Statement

Copyright 1996 Royal Society of Chemistry

Official URL: http://www.rsc.org

DOI: doi:10.1039/AC9963300103

Abstract

The response of phosphate, which is highly variable in capillary zone electrophoresis (CZE) using silica capillaries, was optimized by monitoring the absorption of phosphate onto the capillary surface. A capillary conditioning regime is described which facilitates maximum response for phosphate without significantly extending the total analysis time. The described regime also allowed excellent precision (?0.36%sr, n= 10) to be achieved with regard to absolute migration time for phosphate as well as chloride, bromide, sulfate and hydrogencarbonate. Using this regime, the precisions for the phosphate peak area and height were 9 and 5.5%sr, respectively (n= 10).

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Analytical Chemistry
Research Field:Instrumental Methods (excl. Immunological and Bioassay Methods)
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Harakuwe, AH (Mr Anthony Hekare Harakuwe)
Author:Haddad, PR (Professor Paul Haddad)
ID Code:8657
Year Published:1996
Web of Science® Times Cited:7
Deposited By:Chemistry
Deposited On:1996-08-01
Last Modified:2010-03-14
Downloads:0

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