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Microwave-assisted trans-halogenation reactions of various chloro-, bromo-, trifluoromethanesulfonyloxy- and nonafluorobutanesulfonyloxy-substituted quinolines, isoquinolines, and pyridines leading to the corresponding iodinated heterocycles

Citation

Bissember, AC and Banwell, MG, Microwave-assisted trans-halogenation reactions of various chloro-, bromo-, trifluoromethanesulfonyloxy- and nonafluorobutanesulfonyloxy-substituted quinolines, isoquinolines, and pyridines leading to the corresponding iodinated heterocycles, The Journal of Organic Chemistry, 74, (13) pp. 4893-4895. ISSN 0022-3263 (2009) [Refereed Article]

Copyright Statement

Copyright 2009 American Chemical Society

DOI: doi:10.1021/jo9008386

Abstract

Microwave irradiation of certain chloro-, bromo-, trifluoromethanesulfonyloxy- and nonafluorobutanesulfonyloxy-substituted quinolines in the presence of acetic anhydride and sodium iodide leads, via a trans-halogenation process, to the corresponding iodides in high yield. Related conversions involving pyridines and isoquinolines can also be achieved under similar conditions.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Organic Chemistry
Research Field:Organic Chemical Synthesis
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Bissember, AC (Dr Alex Bissember)
ID Code:85978
Year Published:2009
Web of Science® Times Cited:17
Deposited By:Chemistry
Deposited On:2013-08-19
Last Modified:2013-10-21
Downloads:0

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