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Simultaneous determination of As, Hg, Se and Sb by hydride generation-microwave induced plasma atomic emission spectrometry after preconcentration in a cryogenic trap
journal contribution
posted on 2023-05-17, 18:02 authored by Christian DietzChristian Dietz, Madrid, Y, Quevauviller, P, Camara, CIn this paper a system is presented which combines hydride generation with a preconcentration step in a cryogenic trap and detection using MIP-AES. The MIP has been operating at atmospheric pressure with a forward power of 30-150 W, using a TM010 cavity (Beenakker resonator), equipped with a tangential flow torch design. The plasma emission was observed end-on by the means of a CCD camera coupled to a 0.5 m Czerny-Turner design monochromator. Metal hydrides were generated batchwise in aqueous medium, preconcentrated in a liquid nitrogen cryogenic trap and then evaporated by electrical heating into the plasma discharge. The optimum working conditions have been found at the 197±7 nm window working with a forward power of 130 W, a plasma gas flow rate of 270 ml min–1 of helium, a carrier gas flow rate of 134 ml min–1 of helium, a NaBH4 concentration of 2% and a HNO3 concentration of 0.66 M. Under these conditions detection limits of 2.0, 13, 2.2 and 3.3 µg L–1 for As, Hg, Se and Sb were achieved. The method was applied to the detemination of these analytes in spiked wastewater samples with recoveries of 95% or higher for all four analytes.
History
Publication title
Journal of Analytical Atomic SpectrometryVolume
14Pagination
1349-1355ISSN
0267-9477Publisher
Royal Soc ChemistryPlace of publication
Thomas Graham House, Science Park, Milton Rd, Cambridge, England, Cambs, Cb4 0WfRights statement
Copyright 1999 Royal Society of ChemistryRepository Status
- Restricted