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Crystallographic implications for the design of halogen bonding anion receptors
Citation
Kilah, NL and Wise, MD and Beer, PD, Crystallographic implications for the design of halogen bonding anion receptors, Crystal Growth & Design, 11, (10) pp. 4565-4571. ISSN 1528-7483 (2011) [Refereed Article]
Copyright Statement
Copyright 2011 American Chemical Society
Abstract
X-ray crystallographic analysis has revealed the
bis-halogen bond complexation of chloride and iodide by
4-(4-(tert-butyl)phenyl)-5-iodo-3-methyl-1-n-octyl-1H-1,2,3-
triazol-3-ium cations in two distinct coordination modes. The
chloride complex displays a bent arrangement of the halogen
bonding donors around the central anion (147.84(5) and
142.32(5)o
), while the iodide salt adopts a structure with an
angle closer to orthogonal (78.333(15)o
). The X-ray crystal
structure of a bromide salt of a halogen bonding rotaxane is
also reported. The implications of the angle of halide coordination on the design of interlockedsolution phase halogen
bonding anion receptors are discussed.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Inorganic chemistry |
| Research Field: | Solid state chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding knowledge |
| Objective Field: | Expanding knowledge in the chemical sciences |
| UTAS Author: | Kilah, NL (Dr Nathan Kilah) |
| ID Code: | 84233 |
| Year Published: | 2011 |
| Web of Science® Times Cited: | 47 |
| Deposited By: | Chemistry |
| Deposited On: | 2013-05-01 |
| Last Modified: | 2017-10-25 |
| Downloads: | 0 |
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