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Hemilabile ligands in palladium catalysed C-C linkages: the effect of the donor atom in codimerisation of styrene with ethylene

journal contribution
posted on 2023-05-16, 10:16 authored by Britovsek, GJP, Cavell, KJ, Keim, W
Cationic η3-2-methylallylpalladium(II) complexes with potentially hemilabile ligands XCH2COOEt (X = NPh2, PPh2, OPh, SPh) or methylpicolinate have been prepared and their catalytic properties in the codimerisation of styrene with ethylene have been investigated. The catalytic activity decreases in the order of decreasing trans influence of X: P >> N = O > S > pyr. The relationship between catalytic activity and spectroscopic properties of the complexes is discussed.

History

Publication title

Journal of Molecular Catalysis A: Chemical

Volume

110

Pagination

77-87

ISSN

1381-1169

Department/School

School of Natural Sciences

Publisher

Elsevier Science Bv

Place of publication

The Netherlands

Repository Status

  • Restricted

Socio-economic Objectives

Expanding knowledge in the chemical sciences

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