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Hemilabile ligands in palladium catalysed C-C linkages: the effect of the donor atom in codimerisation of styrene with ethylene
Citation
Britovsek, GJP and Cavell, KJ and Keim, W, Hemilabile ligands in palladium catalysed C-C linkages: the effect of the donor atom in codimerisation of styrene with ethylene, Journal of Molecular Catalysis A: Chemical, 110, (2) pp. 77-87. ISSN 1381-1169 (1996) [Refereed Article]
DOI: doi:10.1016/1381-1169(96)00067-2
Abstract
Cationic η3-2-methylallylpalladium(II) complexes with potentially hemilabile ligands XCH2COOEt (X = NPh2, PPh2, OPh, SPh) or methylpicolinate have been prepared and their catalytic properties in the codimerisation of styrene with ethylene have been investigated. The catalytic activity decreases in the order of decreasing trans influence of X: P >> N = O > S > pyr. The relationship between catalytic activity and spectroscopic properties of the complexes is discussed.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Inorganic Chemistry |
| Research Field: | Transition Metal Chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding Knowledge |
| Objective Field: | Expanding Knowledge in the Chemical Sciences |
| Author: | Britovsek, GJP (Dr George Britovsek) |
| Author: | Cavell, KJ (Professor Kingsley Cavell) |
| ID Code: | 8377 |
| Year Published: | 1996 |
| Web of Science® Times Cited: | 33 |
| Deposited By: | Chemistry |
| Deposited On: | 1996-08-01 |
| Last Modified: | 2011-08-19 |
| Downloads: | 0 |
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