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Hemilabile ligands in palladium catalysed C-C linkages: the effect of the donor atom in codimerisation of styrene with ethylene

Citation

Britovsek, GJP and Cavell, KJ and Keim, W, Hemilabile ligands in palladium catalysed C-C linkages: the effect of the donor atom in codimerisation of styrene with ethylene, Journal of Molecular Catalysis A: Chemical, 110, (2) pp. 77-87. ISSN 1381-1169 (1996) [Refereed Article]

DOI: doi:10.1016/1381-1169(96)00067-2

Abstract

Cationic η3-2-methylallylpalladium(II) complexes with potentially hemilabile ligands XCH2COOEt (X = NPh2, PPh2, OPh, SPh) or methylpicolinate have been prepared and their catalytic properties in the codimerisation of styrene with ethylene have been investigated. The catalytic activity decreases in the order of decreasing trans influence of X: P >> N = O > S > pyr. The relationship between catalytic activity and spectroscopic properties of the complexes is discussed.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Inorganic Chemistry
Research Field:Transition Metal Chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Britovsek, GJP (Dr George Britovsek)
Author:Cavell, KJ (Professor Kingsley Cavell)
ID Code:8377
Year Published:1996
Web of Science® Times Cited:33
Deposited By:Chemistry
Deposited On:1996-08-01
Last Modified:2011-08-19
Downloads:0

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