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Developments in ultra-fast temperature programming with silicon micromachined gas chromatography: Performance and limitations
journal contribution
posted on 2023-05-17, 16:46 authored by Luong, J, Cai, H, Gras, R, Curvers, JVarious commercially available ultra-fast temperature programming approaches were integrated to silicon micromachined GC (micro- GC) for performance improvement assessment. The combined technique of micro-GC and ultra-fast temperature programming up to a rate of 6°C/second yielded an extended analysis range to undecane (nC11), improved signal detectability by at least a factor of three for the solutes studied with respectable one day reproducibility of less than 1% relative standard deviation in retention time (n = 20). Through careful control of various variables affecting retention time, performance improvements can be extended further. The various effects temperature programming has on the stability of thermal conductivity detector as well as criteria that need to be met for the successful implementation of ultra-fast temperature programming in micro-GC are presented.
History
Publication title
Journal of Chromatographic ScienceVolume
50Pagination
245-252ISSN
0021-9665Department/School
School of Natural SciencesPublisher
Preston Publications IncPlace of publication
7800 Merrimac Ave Po Box 48312, Niles, USA, Il, 60648Rights statement
Copyright 2012 The AuthorRepository Status
- Restricted