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An experimental study of carbonated eclogite at 3.5-5.5 GPa - Implications for silicate and carbonate metasomatism in the cratonic mantle


Kiseeva, ES and Yaxley, GM and Hermann, J and Litasov, KD and Rosenthal, A and Kamenetsky, VS, An experimental study of carbonated eclogite at 3.5-5.5 GPa - Implications for silicate and carbonate metasomatism in the cratonic mantle, Journal of Petrology, 53, (4) pp. 727-759. ISSN 0022-3530 (2012) [Refereed Article]

Copyright Statement

Copyright The Author 2012.

DOI: doi:10.1093/petrology/egr078


We have experimentally investigated a K-bearing altered mid-ocean ridge basalt (MORB) composition to which 10% CaCO3 was added (GA1 + 10%cc), at temperatures of 1050-1400C and pressures of 3.5-5.5 GPa. Experiments were conducted in piston-cylinder apparatus in Pt-Gr (Pt with inner graphite) and Au-Pd capsules. Sub-solidus assemblages for both sets of experiments contain clinopyroxene, garnet, carbonate, rutile, coesite and K-feldspar. Apatite was observed only in the Pt-Gr experiments. Melting behaviour in experiments using different capsule materials contrasted markedly. Experiments in Pt-Gr capsules showed the silicate solidus to be at temperatures less than 1100C at 3.5 GPa and less than 1050C at 4.5-5.0 GPa. These are similar (3.5 GPa) or lower (4.5-5.0 GPa) temperatures compared with the carbonate solidus (1075-1125C at 3.5-5.0 GPa). Melts in the Pt-Gr runs evolve with increasing degree of melting from K-rich silicate melts at the lowest degree of melting to carbonate-silicate immiscible liquids and silicate-carbonate melts at intermediate degrees of melting, and finally to silicate melts at the highest degrees of melting. Experiments in Au-Pd capsules were performed only at 5.0 GPa. The carbonate solidus is between 1200 and 1225C (at least 100C higher than in the experiments in Pt-Gr capsules at the same pressure-temperature conditions). The first melts to be produced are carbonatitic and exhibit increasing SiO2 content with increasing temperature. This contrast in melting behaviour is explained by the relatively rapid diffusion of H through the Pt-Gr capsules, resulting in formation of H2O, and thus dramatically depressing both the silicate and the carbonate solidi in the Pt-Gr experiments compared with those in the Au-Pd experiments. This presumably reflects the lower permeability of Au-Pd to H, resulting in a much lower H 2O/CO2 ratio in the Au-Pd encapsulated experiments. The presence of water in the melt was demonstrated by Fourier transform infrared (FTIR) spectroscopic analysis of one Pt-Gr experiment, indicating ~0.5 wt % H 2O in the bulk composition. Further confirmation that H2O plays such a role in the Pt-Gr experiments was provided by an additional experiment performed in a Au-Pd capsule with ~10 wt % H2O specifically added. In this experiment immiscible carbonate and silicate melts were observed. Carbonate-silicate liquid immiscibility is considered to occur as a result of the H2O present in the system. These results can be applied to natural systems in several ways. First, the presence of a small amount of either silicate melt or H2O-fluid in the system will act as a 'flux', depressing the carbonate solidus to much lower temperatures than in anhydrous systems. Second, the full trend in melt evolution from silicate-rich to carbonate-rich melts, which is also observed in inclusions in diamonds, can be explained by melting of K- and CO2-bearing, water-undersaturated MORB compositions. In cratonic environments low-degree silicate and immiscible silicate and carbonate melts will metasomatize the overlying mantle in different ways, producing, in the first instance, Si enrichment and crystallization of additional orthopyroxene, phlogopite, pyrope-rich garnet and consuming olivine, and, in the second case, carbonate metasomatism, with additional magnesite-dolomite, clinopyroxene and apatite. Both metasomatic styles have been described in natural peridotite xenoliths from the cratonic lithosphere.

Item Details

Item Type:Refereed Article
Research Division:Earth Sciences
Research Group:Geology
Research Field:Igneous and metamorphic petrology
Objective Division:Expanding Knowledge
Objective Group:Expanding knowledge
Objective Field:Expanding knowledge in the earth sciences
UTAS Author:Kamenetsky, VS (Professor Vadim Kamenetsky)
ID Code:81365
Year Published:2012
Funding Support:Australian Research Council (DP1092823)
Web of Science® Times Cited:113
Deposited By:Centre for Ore Deposit Research - CODES CoE
Deposited On:2012-12-03
Last Modified:2014-02-03

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