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Pt(PEt3)(k2-P,C-PEt2CHMe)(C6Cl5): An unexpected intermediate in the synthesis of cis-Pt(PEt3)2(Cl)(C6Cl5)

journal contribution
posted on 2023-05-17, 14:31 authored by Robinson, R, Clarkson, JM, Moody, MA, Sharp, PR
Addition of 1 to 6 equiv of LiC6Cl5 to cis-Pt(PEt3)2Cl2 gives the unexpected phosphine ligand C-H bond activation product Pt(PEt3)(ê2-P,C-PEt2CHMe)(C6Cl5) (1). Aqueous HCl addition to 1 gives the previously reported product of the reaction, cis-Pt(PEt3)2(Cl)(C6Cl5) (2).

History

Publication title

Organometallics

Volume

30

Issue

6

Pagination

1730-1733

ISSN

0276-7333

Department/School

School of Natural Sciences

Publisher

Amer Chemical Soc

Place of publication

1155 16Th St, Nw, Washington, USA, Dc, 20036

Rights statement

Copyright 2011 American Chemical Society

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  • Restricted

Socio-economic Objectives

Expanding knowledge in the chemical sciences

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