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Pt(PEt3)(k2-P,C-PEt2CHMe)(C6Cl5): An unexpected intermediate in the synthesis of cis-Pt(PEt3)2(Cl)(C6Cl5)

Citation

Robinson, R and Clarkson, JM and Moody, MA and Sharp, PR, Pt(PEt3)(k2-P,C-PEt2CHMe)(C6Cl5): An unexpected intermediate in the synthesis of cis-Pt(PEt3)2(Cl)(C6Cl5), Organometallics, 30, (6) pp. 1730-1733. ISSN 0276-7333 (2010) [Refereed Article]

Copyright Statement

Copyright 2011 American Chemical Society

DOI: doi:10.1021/om1010879

Abstract

Addition of 1 to 6 equiv of LiC6Cl5 to cis-Pt(PEt3)2Cl2 gives the unexpected phosphine ligand C-H bond activation product Pt(PEt3)(2-P,C-PEt2CHMe)(C6Cl5) (1). Aqueous HCl addition to 1 gives the previously reported product of the reaction, cis-Pt(PEt3)2(Cl)(C6Cl5) (2).

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Inorganic Chemistry
Research Field:Transition Metal Chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Robinson, R (Dr Robert Robinson)
ID Code:81051
Year Published:2010
Web of Science® Times Cited:3
Deposited By:Chemistry
Deposited On:2012-11-22
Last Modified:2013-05-08
Downloads:0

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