eCite Digital Repository

Synthesis of perimidine and fused perimidine derivatives from reaction of 1,8-naphthalenediamine with an iminoisocoumarin

Citation

Deady, LW and Rodemann, T, Synthesis of perimidine and fused perimidine derivatives from reaction of 1,8-naphthalenediamine with an iminoisocoumarin, Journal of Heterocyclic Chemistry: International Journal, 35, (6) pp. 1417-1419. ISSN 0022-152X (1998) [Refereed Article]

DOI: doi:10.1002/jhet.5570350633

Abstract

The isocoumarin deriv. 1H-1-(acetylimino)-3-methylbenzo[c]pyran-4-carbonitrile reacts with 1,8-naphthalenediamine under basic conditions to give, primarily, the acetylisoquino[2,1-a]perimidinamine I. I underwent a variety of reactions to give other isoquino[2,1-a]perimidine derivs., ring opening to 2-(1H-perimidin-2-yl)phenylacetic acids and, in polyphosphoric acid, a new hexacyclic system, 6-methyl-7,13,13d-triazadibenzo[def,qr]chrysene (II).

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Organic Chemistry
Research Field:Organic Chemical Synthesis
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Rodemann, T (Dr Thomas Rodemann)
ID Code:80359
Year Published:1998
Web of Science® Times Cited:24
Deposited By:Central Science Laboratory
Deposited On:2012-10-30
Last Modified:2012-10-30
Downloads:0

Repository Staff Only: item control page