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Synthesis of perimidine and fused perimidine derivatives from reaction of 1,8-naphthalenediamine with an iminoisocoumarin
Citation
Deady, LW and Rodemann, T, Synthesis of perimidine and fused perimidine derivatives from reaction of 1,8-naphthalenediamine with an iminoisocoumarin, Journal of Heterocyclic Chemistry: International Journal, 35, (6) pp. 1417-1419. ISSN 0022-152X (1998) [Refereed Article]
DOI: doi:10.1002/jhet.5570350633
Abstract
The isocoumarin deriv. 1H-1-(acetylimino)-3-methylbenzo[c]pyran-4-carbonitrile reacts with 1,8-naphthalenediamine under basic conditions to give, primarily, the acetylisoquino[2,1-a]perimidinamine I. I underwent a variety of reactions to give other isoquino[2,1-a]perimidine derivs., ring opening to 2-(1H-perimidin-2-yl)phenylacetic acids and, in polyphosphoric acid, a new hexacyclic system, 6-methyl-7,13,13d-triazadibenzo[def,qr]chrysene (II).
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Organic Chemistry |
| Research Field: | Organic Chemical Synthesis |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding Knowledge |
| Objective Field: | Expanding Knowledge in the Chemical Sciences |
| Author: | Rodemann, T (Dr Thomas Rodemann) |
| ID Code: | 80359 |
| Year Published: | 1998 |
| Web of Science® Times Cited: | 22 |
| Deposited By: | Central Science Laboratory |
| Deposited On: | 2012-10-30 |
| Last Modified: | 2012-10-30 |
| Downloads: | 0 |
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