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Structure of wood extract colloids and effect of CaCl 2 on the molecular mobility

Citation

Lee, R and Stack, K and Lewis, TW and Garnier, G and Richardson, D and Ottaviani, MF and Jockusch, S and Turro, NJ, Structure of wood extract colloids and effect of CaCl 2 on the molecular mobility, Nordic Pulp and Paper Research Journal, 27, (3) pp. 639-646. ISSN 0283-2631 (2012) [Refereed Article]


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Copyright Statement

Copyright 2012 The authors.

DOI: doi:10.3183/NPPRJ-2012-27-03-p639-646

Abstract

Electron paramagnetic resonance (EPR) was used to study the colloidal structure of model wood extractive colloids composed of a resin acid (abietic acid), a fatty acid (oleic acid) and a triglyceride (triolein). Two nitroxides were chosen as EPR probes to gain a greater understanding of the different regions of the colloid in order to assess the current proposed models of the structure of the wood extractive colloid. A non-polar nitroxide probed non-polar regions of the colloid, such as triglycerides, while a surfactant-type nitroxide probed regions occupied by fatty acids. The effect of varying the amounts of each of the model colloid components on the structure of the colloid and its interaction with the probe was investigated. Results of the EPR study confirm the existence of a hydrophobic core. However, surface tension and EPR results suggest that the outer layer of the colloid is composed of mostly resin acids. It is proposed that a fatty acid layer exists between the resin acids and triglycerides and is sufficiently mobile to move between them. The addition of salt (CaCl2) was found to affect the mobility of molecules at the core of the colloid.

Item Details

Item Type:Refereed Article
Keywords:wood resin, pitch, colloid structure, electron paramagnetic resonance spectroscopy, EPR
Research Division:Chemical Sciences
Research Group:Physical Chemistry (incl. Structural)
Research Field:Colloid and Surface Chemistry
Objective Division:Manufacturing
Objective Group:Wood, Wood Products and Paper
Objective Field:Pulp and Paper
Author:Lee, R (Mr Roland Lee)
Author:Stack, K (Dr Karen Stack)
Author:Lewis, TW (Dr Trevor Lewis)
ID Code:79792
Year Published:2012
Web of Science® Times Cited:4
Deposited By:Chemistry
Deposited On:2012-10-03
Last Modified:2013-04-22
Downloads:0

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