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Facile synthesis and coupling of functionalized isomeric biquinolines
journal contribution
posted on 2023-05-17, 12:28 authored by Tomar, M, Lucas, NT, Michael GardinerMichael Gardiner, Mullen, K, Jacob, JA simple route toward functionalized biquinolines, namely 8,5'-dibromo-5,8'-biquinoline 1 and 5,5'-dibromo-8,8'-biquinoline 2, was developed using Skraup syntheses. Both the dibromo compounds undergo facile Suzuki coupling to afford fluorene-coupled products 3 and 4, respectively, an important transformation in designing conjugated materials based on these cores. X-ray structural analyses of 1 and 4 provide insight into the mode of packing within materials containing these units.
History
Publication title
Tetrahedron LettersVolume
53Pagination
285-288ISSN
0040-4039Department/School
School of Natural SciencesPublisher
Pergamon-Elsevier Science LtdPlace of publication
OxfordRights statement
Copyright 2011 Elsevier LtdRepository Status
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