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Facile synthesis and coupling of functionalized isomeric biquinolines

Citation

Tomar, M and Lucas, NT and Gardiner, MG and Mullen, K and Jacob, J, Facile synthesis and coupling of functionalized isomeric biquinolines, Tetrahedron Letters, 53, (3) pp. 285-288. ISSN 0040-4039 (2012) [Refereed Article]

Copyright Statement

Copyright 2011 Elsevier Ltd

DOI: doi:10.1016/j.tetlet.2011.11.008

Abstract

A simple route toward functionalized biquinolines, namely 8,5'-dibromo-5,8'-biquinoline 1 and 5,5'-dibromo-8,8'-biquinoline 2, was developed using Skraup syntheses. Both the dibromo compounds undergo facile Suzuki coupling to afford fluorene-coupled products 3 and 4, respectively, an important transformation in designing conjugated materials based on these cores. X-ray structural analyses of 1 and 4 provide insight into the mode of packing within materials containing these units.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Macromolecular and Materials Chemistry
Research Field:Optical Properties of Materials
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Gardiner, MG (Associate Professor Michael Gardiner)
ID Code:78556
Year Published:2012
Web of Science® Times Cited:4
Deposited By:Chemistry
Deposited On:2012-07-07
Last Modified:2015-08-10
Downloads:0

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