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Boron-Mediated Stereoselective Syntheses of γ,γ-Disubstituted Allenamides


Hyland, CJT and Hegedus, LS, Boron-Mediated Stereoselective Syntheses of γ,γ-Disubstituted Allenamides, The Journal of Organic Chemistry, 70, (21) pp. 8628-8630. ISSN 0022-3263 (2005) [Refereed Article]

DOI: doi:10.1021/jo051385c


Propargylic boranes generated by lithiation of optically active N-propargyloxazolidinones undergo reaction with a range of aldehydes to produce γ,γ-disubstituted allenamides with good diastereoselectivity.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Organic chemistry
Research Field:Organic chemical synthesis
Objective Division:Expanding Knowledge
Objective Group:Expanding knowledge
Objective Field:Expanding knowledge in the chemical sciences
ID Code:73762
Year Published:2005
Web of Science® Times Cited:18
Deposited By:Chemistry
Deposited On:2011-10-25
Last Modified:2011-10-25

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