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Regularities of Retention of Benzoic Acids on Microdispersed Detonation Nanodiamonds in Water–Methanol Mobile Phases
journal contribution
posted on 2023-05-17, 07:56 authored by Fedyanina, ON, Nesterenko, PNThe dependences of the retention of phenols on microdispersed sintered detonation nanodiamond (MSDN) were studied. It was shown that when there is a high content of acetonitrile and methanol in aqueous-organic eluents, the retention of the studied compounds on MSDN is accomplished by the mechanism of normal-phase liquid chromatography due to hydrophilic interactions of different natures. It was found that the retention of phenols is inversely proportional to the acidity of phenol groups and can be used for their selective separation.
History
Publication title
Russian Journal of Physical Chemistry AVolume
85Issue
10Pagination
1773-1777ISSN
0036-0244Department/School
School of Natural SciencesPublisher
InterperiodicaPlace of publication
PO Box 1831, Birmingham, USA, Al, 35201-1831Rights statement
Copyright 2011 Pleiades Publishing, Ltd.Repository Status
- Restricted