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Versatile Capillary Column Temperature Control Using a Thermoelectric Array Based Platform

Citation

Collins, D and Nesterenko, E and Connolly, D and Vasquez, M and Macka, M and Brabazon, D and Paull, B, Versatile Capillary Column Temperature Control Using a Thermoelectric Array Based Platform, Analytical Chemistry, 83, (11) pp. 4307-4313. ISSN 0003-2700 (2011) [Refereed Article]


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Copyright Statement

Copyright 2011 American Chemical Society

DOI: doi:10.1021/ac2004955

Abstract

A new direct contact platform for capillary column precise temperature control based upon the use of individually controlled sequentially aligned Peltier thermoelectric units is presented. The platform provides rapid temperature control for capillary and microbore liquid chromatography columns and allows simultaneous temporal and spatial temperature programming. The operating temperature range of the platform was between 15 and 200 degrees C for each of 10 aligned Peltier units, with a ramp rate of approximately 400 degrees C/min. The system was evaluated for a number of nonstandard capillary based applications, such as the direct application of temperature gradients with both linear and nonlinear profiles, including both static column temperature gradients and temporal temperature gradients, and the formation of in-capillary monolithic stationary phases with gradient polymerization through precise temperature control

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Analytical Chemistry
Research Field:Separation Science
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Macka, M (Professor Mirek Macka)
Author:Paull, B (Professor Brett Paull)
ID Code:72680
Year Published:2011
Web of Science® Times Cited:20
Deposited By:Chemistry
Deposited On:2011-08-30
Last Modified:2012-05-10
Downloads:0

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