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Structural Chemistry of [MX2(bipy)] (M = Pd, Pt; X = Cl, Br, I): the Yellow Polymorph of Dichlorido(2,2'-bipyridine) platinum(II) and Diiodido(2,2'-bipyridine)palladium(II), and Overview of this System
Citation
Canty, AJ and Gardiner, MG and Jones, RC and Sharma, M, Structural Chemistry of [MX2(bipy)] (M = Pd, Pt; X = Cl, Br, I): the Yellow Polymorph of Dichlorido(2,2'-bipyridine) platinum(II) and Diiodido(2,2'-bipyridine)palladium(II), and Overview of this System, Australian Journal of Chemistry, 64, (9) pp. 1355-1359. ISSN 0004-9425 (2011) [Refereed Article]
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Copyright Statement
Copyright 2011 CSIRO
DOI: doi:10.1071/CH11095
Abstract
Synchrotron data have been used to determine the structures of the yellow polymorph of dichlorido(2,2'-bipyridine)platinum(II) (1), and diiodido(2,2'-bipyridine)palladium(II) (2), allowing a detailed comparison of the crystal chemistry of [MX2(bipy)] (M = Pd, Pt; X = Cl, Br, I) which exhibit polymorphism involving nine structures distributed over five space groups. Complex 1 crystallizes in space group Pbca (a = 18.2540(7), b = 15.6970(7), c = 7.3560(6) Å), and 2 in space group C2/c (a = 17.149(1), b = 9.8050(8), c = 7.548(1)Å, β = 110.72(1) °).
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Inorganic Chemistry |
| Research Field: | Transition Metal Chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding Knowledge |
| Objective Field: | Expanding Knowledge in the Chemical Sciences |
| Author: | Canty, AJ (Professor Allan Canty) |
| Author: | Gardiner, MG (Associate Professor Michael Gardiner) |
| Author: | Jones, RC (Dr Roderick Jones) |
| Author: | Sharma, M (Dr Manab Sharma) |
| ID Code: | 72635 |
| Year Published: | 2011 |
| Web of Science® Times Cited: | 7 |
| Deposited By: | Chemistry |
| Deposited On: | 2011-08-30 |
| Last Modified: | 2012-07-30 |
| Downloads: | 0 |
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