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Structural Chemistry of [MX2(bipy)] (M = Pd, Pt; X = Cl, Br, I): the Yellow Polymorph of Dichlorido(2,2'-bipyridine) platinum(II) and Diiodido(2,2'-bipyridine)palladium(II), and Overview of this System

Citation

Canty, AJ and Gardiner, MG and Jones, RC and Sharma, M, Structural Chemistry of [MX2(bipy)] (M = Pd, Pt; X = Cl, Br, I): the Yellow Polymorph of Dichlorido(2,2'-bipyridine) platinum(II) and Diiodido(2,2'-bipyridine)palladium(II), and Overview of this System, Australian Journal of Chemistry, 64, (9) pp. 1355-1359. ISSN 0004-9425 (2011) [Refereed Article]


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Copyright 2011 CSIRO

DOI: doi:10.1071/CH11095

Abstract

Synchrotron data have been used to determine the structures of the yellow polymorph of dichlorido(2,2'-bipyridine)platinum(II) (1), and diiodido(2,2'-bipyridine)palladium(II) (2), allowing a detailed comparison of the crystal chemistry of [MX2(bipy)] (M = Pd, Pt; X = Cl, Br, I) which exhibit polymorphism involving nine structures distributed over five space groups. Complex 1 crystallizes in space group Pbca (a = 18.2540(7), b = 15.6970(7), c = 7.3560(6) Å), and 2 in space group C2/c (a = 17.149(1), b = 9.8050(8), c = 7.548(1)Å, β = 110.72(1) °).

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Inorganic Chemistry
Research Field:Transition Metal Chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
UTAS Author:Canty, AJ (Professor Allan Canty)
UTAS Author:Gardiner, MG (Associate Professor Michael Gardiner)
UTAS Author:Jones, RC (Dr Roderick Jones)
UTAS Author:Sharma, M (Dr Manab Sharma)
ID Code:72635
Year Published:2011
Web of Science® Times Cited:15
Deposited By:Chemistry
Deposited On:2011-08-30
Last Modified:2018-04-16
Downloads:0

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