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Experimental and theoretical investigation into the gold-catalyzed reactivity of cyclopropenylmethyl acetates

Citation

Seraya, E and Slack, E and Ariafard, A and Yates, BF and Hyland, CJT, Experimental and theoretical investigation into the gold-catalyzed reactivity of cyclopropenylmethyl acetates, Organic Letters, 12, (21) pp. 4768-4771. ISSN 1523-7060 (2010) [Refereed Article]

DOI: doi:10.1021/ol101862u

Abstract

Cyclopropenylmethyl acetates have been shown to undergo rapid and stereoselective gold catalyzed rearrangement to Z-acetoxydienes in high yield. DFT calculations have shown that while several reaction pathways can be envisaged only a single, ring-opening one operates. © 2010 American Chemical Society.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Other Chemical Sciences
Research Field:Organometallic Chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Ariafard, A (Associate Professor Alireza Ariafard)
Author:Yates, BF (Professor Brian Yates)
Author:Hyland, CJT (Dr Chris Hyland)
ID Code:67759
Year Published:2010
Web of Science® Times Cited:20
Deposited By:Chemistry
Deposited On:2011-03-07
Last Modified:2011-05-04
Downloads:0

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