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Experimental and theoretical investigation into the gold-catalyzed reactivity of cyclopropenylmethyl acetates

journal contribution
posted on 2023-05-17, 05:00 authored by Seraya, E, Slack, E, Alireza AriafardAlireza Ariafard, Brian YatesBrian Yates, Hyland, CJT
Cyclopropenylmethyl acetates have been shown to undergo rapid and stereoselective gold catalyzed rearrangement to Z-acetoxydienes in high yield. DFT calculations have shown that while several reaction pathways can be envisaged only a single, ring-opening one operates. © 2010 American Chemical Society.

History

Publication title

Organic Letters

Volume

12

Issue

21

Pagination

4768-4771

ISSN

1523-7060

Department/School

School of Natural Sciences

Publisher

Amer Chemical Soc

Place of publication

1155 16Th St, Nw, Washington, USA, Dc, 20036

Repository Status

  • Restricted

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Expanding knowledge in the chemical sciences

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