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Experimental and theoretical investigation into the gold-catalyzed reactivity of cyclopropenylmethyl acetates
Citation
Seraya, E and Slack, E and Ariafard, A and Yates, BF and Hyland, CJT, Experimental and theoretical investigation into the gold-catalyzed reactivity of cyclopropenylmethyl acetates, Organic Letters, 12, (21) pp. 4768-4771. ISSN 1523-7060 (2010) [Refereed Article]
Abstract
Cyclopropenylmethyl acetates have been shown to undergo rapid and stereoselective gold catalyzed rearrangement to Z-acetoxydienes in high yield. DFT calculations have shown that while several reaction pathways can be envisaged only a single, ring-opening one operates. © 2010 American Chemical Society.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Other Chemical Sciences |
| Research Field: | Organometallic Chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding Knowledge |
| Objective Field: | Expanding Knowledge in the Chemical Sciences |
| UTAS Author: | Ariafard, A (Associate Professor Alireza Ariafard) |
| UTAS Author: | Yates, BF (Professor Brian Yates) |
| UTAS Author: | Hyland, CJT (Dr Chris Hyland) |
| ID Code: | 67759 |
| Year Published: | 2010 |
| Web of Science® Times Cited: | 32 |
| Deposited By: | Chemistry |
| Deposited On: | 2011-03-07 |
| Last Modified: | 2011-05-04 |
| Downloads: | 0 |
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