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Dimethylcuprate undergoes a dyotropic rearrangement
Citation
Rijs, NJ and Yates, BF and O'Hair, RAJ, Dimethylcuprate undergoes a dyotropic rearrangement, Chemistry: A European Journal, 16, (9) pp. 2674-2678. ISSN 0947-6539 (2010) [Refereed Article]
DOI: doi:10.1002/chem.200903510
Abstract
All change! Comparison of the gasphase decomposition reactions of [CH 3CuCH3]- and [CH3AgCH 3]- reveals that [CH3CuCH3] - undergoes a competition between a dyotropic rearrangement and bond homolysis, whilst [CH3AgCH3]- only undergoes bond homolysis. Ab initio calculations reveal that the different behavior in [CH3AgCH3]- stems from both the lowering of the homolytic bond dissociation energy and an increase in dyotropic rearrangement activation energy. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Other Chemical Sciences |
| Research Field: | Organometallic Chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding Knowledge |
| Objective Field: | Expanding Knowledge in the Chemical Sciences |
| Author: | Yates, BF (Professor Brian Yates) |
| ID Code: | 67751 |
| Year Published: | 2010 |
| Web of Science® Times Cited: | 32 |
| Deposited By: | Chemistry |
| Deposited On: | 2011-03-07 |
| Last Modified: | 2011-05-04 |
| Downloads: | 0 |
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