eCite Digital Repository
Two-step stacking in capillary zone electrophoresis featuring sweeping and micelle to solvent stacking: I. Organic cations
Citation
Quirino, JP, Two-step stacking in capillary zone electrophoresis featuring sweeping and micelle to solvent stacking: I. Organic cations, Journal of Chromatography A, 1217, (49) pp. 7776-7780. ISSN 0021-9673 (2010) [Refereed Article]
 | PDF Restricted - Request a copy 630Kb | | PDF (Supplementary Information) Restricted - Request a copy 63Kb |
Copyright Statement
The definitive version is available at http://www.sciencedirect.com
Official URL: http://www.sciencedirect.com
DOI: doi:10.1016/j.chroma.2010.10.020
Abstract
Two-step stacking of organic cations by sweeping and micelle to solvent stacking (MSS) in capillary zone electrophoresis (CZE) is presented. The simple procedure involves hydrodynamic injection of a micellar sodium dodecyl sulfate solution before the sample that is prepared without the micelles. The micelles sweep and transport the cations to the boundary zone between the sample and CZE buffer. The presence of organic solvent in the CZE buffer induces the second stacking step of MSS. The LODs obtained for the four beta blocker and two tricyclic antidepressant test drugs were 20–50 times better compared to typical injection.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Keywords: | On-line sample concentration; Sweeping; Micelle to solvent stacking; Capillary zone electrophoresis; Beta blocker drugs; Tricyclics antidepressant drugs |
| Research Division: | Chemical Sciences |
| Research Group: | Analytical Chemistry |
| Research Field: | Separation Science |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding Knowledge |
| Objective Field: | Expanding Knowledge in the Chemical Sciences |
| UTAS Author: | Quirino, JP (Associate Professor Lito Quirino) |
| ID Code: | 65516 |
| Year Published: | 2010 |
| Web of Science® Times Cited: | 35 |
| Deposited By: | Austn Centre for Research in Separation Science |
| Deposited On: | 2010-11-22 |
| Last Modified: | 2014-10-17 |
| Downloads: | 0 |
Repository Staff Only: item control page