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Reduction of a chelating bis(NHC) palladium(II) complex to [{mu-bis(NHC)}2Pd2H]<+>+<->: A terminal hydride in a binuclear palladium(I) species formed under catalytically relevant conditions

Citation

Boyd, PDW and Edwards, AJ and Gardiner, MG and Ho, CC and Lemee-Cailleau, MH and McGuinness, DS and Riapanitra, A and Steed, JW and Stringer, DN and Yates, BF, Reduction of a chelating bis(NHC) palladium(II) complex to [{mu-bis(NHC)}2Pd2H]<+>+<->: A terminal hydride in a binuclear palladium(I) species formed under catalytically relevant conditions, Angewandte Chemie International Edition, 49, (36) pp. 6315-6318. ISSN 1433-7851 (2010) [Refereed Article]

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The definitive published version is available online at: http://onlinelibrary.wiley.com/

Official URL: http://onlinelibrary.wiley.com/

DOI: doi:10.1002/anie.201003177

Abstract

Catalytic processes featuring N-heterocyclic carbene (NHC) ligands have been extensively studied following the isolation of free imidazol-2-ylidenes An important reaction class is the base-assisted palladium-mediated C–C/N coupling, such as the Sonogashira, Buchwald–Hartwig, and Mizoroki–Heck reactions

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Inorganic Chemistry
Research Field:Transition Metal Chemistry
Objective Division:Manufacturing
Objective Group:Industrial Chemicals and Related Products
Objective Field:Inorganic Industrial Chemicals
Author:Boyd, PDW (Associate Professor Peter Boyd)
Author:Gardiner, MG (Associate Professor Michael Gardiner)
Author:Ho, CC (Dr Curtis Ho)
Author:McGuinness, DS (Dr David McGuinness)
Author:Riapanitra, A (Mr Anung Riapanitra)
Author:Stringer, DN (Mr Damien Stringer)
Author:Yates, BF (Professor Brian Yates)
ID Code:64669
Year Published:2010
Web of Science® Times Cited:26
Deposited By:Chemistry
Deposited On:2010-08-16
Last Modified:2012-04-21
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