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Reduction of a chelating bis(NHC) palladium(II) complex to [{mu-bis(NHC)}2Pd2H]+: A terminal hydride in a binuclear palladium(I) species formed under catalytically relevant conditions
journal contribution
posted on 2023-05-17, 03:03 authored by Boyd, PDW, Edwards, AJ, Michael GardinerMichael Gardiner, Curtis HoCurtis Ho, Lemee-Cailleau, MH, McGuinness, DS, Riapanitra, A, Steed, JW, Stringer, DN, Brian YatesBrian YatesCatalytic processes featuring N-heterocyclic carbene (NHC) ligands have been extensively studied following the isolation of free imidazol-2-ylidenes An important reaction class is the base-assisted palladium-mediated C–C/N coupling, such as the Sonogashira, Buchwald–Hartwig, and Mizoroki–Heck reactions
History
Publication title
Angewandte Chemie International EditionVolume
49Issue
36Pagination
6315-6318ISSN
1433-7851Department/School
School of Natural SciencesPublisher
Wiley-BlackwellPlace of publication
Malden, USARights statement
The definitive published version is available online at: http://onlinelibrary.wiley.com/Repository Status
- Restricted