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Organopalladium and platinum chemistry in oxidising milieu as models for organic synthesis involving the higher oxidation states of palladium
Citation
Canty, AJ, Organopalladium and platinum chemistry in oxidising milieu as models for organic synthesis involving the higher oxidation states of palladium, Dalton Transactions, 2009, (47) pp. 10409-10417. ISSN 1477-9226 (2009) [Refereed Article]
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DOI: doi:10.1039/B914080H
Abstract
This perspective focuses on the higher oxidation state palladium(III) and palladium(IV)organometallic chemistry involving a range of strong oxidants, with consideration of platinum(III) and platinum(IV) chemistry where it is informative for the evaluation of structure and mechanism. Particular emphasis is placed on hypervalent iodine reagents, halogens and related oxidants of intense current interest in organic synthesis, together with linkages in concepts between this chemistry and recent advances in studies of diaryl disulfides, diaryl diselenides, and diaryl peroxides as oxidants. The chemistry of binuclear metal-metal bonded complexes of palladium and platinum is discussed.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Other Chemical Sciences |
| Research Field: | Organometallic Chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding Knowledge |
| Objective Field: | Expanding Knowledge in the Chemical Sciences |
| Author: | Canty, AJ (Professor Allan Canty) |
| ID Code: | 62412 |
| Year Published: | 2009 |
| Web of Science® Times Cited: | 93 |
| Deposited By: | Chemistry |
| Deposited On: | 2010-03-12 |
| Last Modified: | 2012-10-05 |
| Downloads: | 0 |
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