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C11-Chirasil-Dex as chiral stationary phase in GC: enantioselective separation of cyclopropane derivatives
journal contribution
posted on 2023-05-17, 00:16 authored by Ghanem, AChirasil-â-Dex containing an undecamethylene spacer (C11-Chirasil-Dex) was used as chiral stationary phase (CSP) in enantioselective gas chromatography (GC). The versatility of the new stationary phase in the simultaneous enantiomeric separation of a set of cyclopropane derivatives is demonstrated. The GC method provides information about the chemical yields of the cyclopropane products, enantioselectivity, substrate specifity, and catalytic activity of the chiral catalysts used in the intermolecular cyclopropanation of olefins and avoids time-consuming work-up procedures.
History
Publication title
TalantaVolume
66Issue
5Pagination
1234-1241ISSN
0039-9140Department/School
School of Natural SciencesPublisher
Elsevier Science BvPlace of publication
Po Box 211, Amsterdam, Netherlands, 1000 AeRights statement
The definitive version is available at http://www.sciencedirect.comRepository Status
- Restricted