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Enantioselective gas chromatographic analysis of cyclopropane derivatives


Ghanem, A and Aboul-Enein, HY and Lacrampe, F and Jiang, Z and Grass, S and Muller, P, Enantioselective gas chromatographic analysis of cyclopropane derivatives, Chromatographia, 61, (3-4) pp. 103-111. ISSN 0009-5893 (2005) [Refereed Article]

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DOI: doi:10.1365/s10337-004-0425-3


Chirasil-beta-Dex was used as chiral stationary phase for the enantioselective gas chromatographic analysis of several new chiral cyclopropane derivatives. The GC method provides information about the chemical yields of the cyclopropane products, enantioselectivity, substrate specifity, and catalytic activity of the chiral catalysts used in the inter- and intra-molecular cyclopropanation reactions and avoids time-consuming work-up procedures.

Item Details

Item Type:Refereed Article
Keywords:Gas chromatography - Enantiomeric excess - Chirasil-beta-Dex - Rhodium complexes - Cyclopropanes
Research Division:Chemical Sciences
Research Group:Organic chemistry
Research Field:Organic chemical synthesis
Objective Division:Expanding Knowledge
Objective Group:Expanding knowledge
Objective Field:Expanding knowledge in the chemical sciences
UTAS Author:Ghanem, A (Dr Ashraf Ghanem)
ID Code:57760
Year Published:2005
Web of Science® Times Cited:7
Deposited By:Austn Centre for Research in Separation Science
Deposited On:2009-08-12
Last Modified:2009-08-13

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