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Chirasil-â-dex with a new C11-spacer for enantioselective gas chromatography. Application to the kinetic resolution of secondary alcohols catalyzed by lipase
Citation
Ghanem, A and Ginatta, C and Jian, Z and Schurig, V, Chirasil-a-dex with a new C11-spacer for enantioselective gas chromatography. Application to the kinetic resolution of secondary alcohols catalyzed by lipase, Chromatographia, 57, (Supplement 1) pp. S275-S281. ISSN 0009-5893 (2003) [Refereed Article]
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Abstract
Chirasil-â-Dex containing an undecamethylene spacer (C11-Chirasil-Dex) was synthesized and used as a chiral stationary phase (CSP) in enantioselective GC. The versatility of the new CSP for the simultaneous enantiomeric separation of underivatized secondary alcohols and their corresponding acetates is demonstrated. The determination of enantiomeric excesses, ee, of substrate and product resulting from the lipase-catalyzed transesterification of secondary alcohols with isopropenylacetate in toluene was investigated using the title CSP.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Keywords: | Gas chromatography - Enantiomeric separations - C11-Chirasil-â-Dex stationary phase - Secondary alcohols - Enzymatic kinetic resolution |
| Research Division: | Chemical Sciences |
| Research Group: | Analytical Chemistry |
| Research Field: | Separation Science |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding Knowledge |
| Objective Field: | Expanding Knowledge in the Chemical Sciences |
| UTAS Author: | Ghanem, A (Dr Ashraf Ghanem) |
| ID Code: | 57757 |
| Year Published: | 2003 |
| Web of Science® Times Cited: | 21 |
| Deposited By: | Austn Centre for Research in Separation Science |
| Deposited On: | 2009-08-12 |
| Last Modified: | 2009-08-13 |
| Downloads: | 0 |
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