eCite Digital Repository

High-performance liquid chromatography of -amino acid enantiomers on eremomycin-modified silica


Kuznetsov, MA and Nesterenko, PN and Vasiyarov, GG and Staroverov, SM, High-performance liquid chromatography of a-amino acid enantiomers on eremomycin-modified silica, Journal of Analytical Chemistry, 63, (1) pp. 57-64. ISSN 1061-9348 (2008) [Refereed Article]

DOI: doi:10.1007/s10809-008-1011-x


The chromatographic behavior of enantiomers of α-amino acids was studied on new chiral stationary phases based on silica gel with macrocyclic glycopeptide antibiotic eremomycin and its aglycone immobilized on the surface. The retention of adsorbates and enantioselectivity of their separation were studied as functions of the structure of the side group of α-amino acids, eluant pH, concentration of organic modifier in the eluant, and temperature. The mechanism of the chiral recognition of α-amino acid enantiomers is discussed. © 2008 MAIK Nauka.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Analytical chemistry
Research Field:Separation science
Objective Division:Expanding Knowledge
Objective Group:Expanding knowledge
Objective Field:Expanding knowledge in the chemical sciences
UTAS Author:Nesterenko, PN (Professor Pavel Nesterenko)
ID Code:55180
Year Published:2008
Web of Science® Times Cited:26
Deposited By:Chemistry
Deposited On:2009-03-06
Last Modified:2009-05-01

Repository Staff Only: item control page