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Microfluidic devices for flow-through supported palladium catalysis on porous organic monolith
Citation
Canty, AJ and Deverell, JA and Goemann, A and Guijt, RM and Rodemann, T and Smith, Jason, Microfluidic devices for flow-through supported palladium catalysis on porous organic monolith, Australian Journal of Chemistry, 61, (8) pp. 630-633. ISSN 0004-9425 (2008) [Refereed Article]
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Copyright Statement
© CSIRO 2008
DOI: doi:10.1071/CH08160
Abstract
Flow-through microreactors are described, constructed of fused silica capillaries with an internal diameter of 100μm and glass microchips with a channel dimension of 150μm and involving the in situ UV-initiated synthesis of a poly(glycidyl methacrylate-co-ethylene dimethacrylate) porous polymer monolith. The monolith is a continuous material covalently bonded to the capillary or chip walls, with good flow-through properties. Epoxide ring-opening through amine attack by 5-amino-1,10-phenanthroline and coordination to dichloropalladium(ii) allows use of the microreactors for Suzuki–Miyaura catalysis. The long-term stability and reliability of the robust lab on a chip microreactor is demonstrated by operation for 96 h, exhibiting undiminished reactivity, and very low leaching of palladium.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Inorganic Chemistry |
| Research Field: | Transition Metal Chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding Knowledge |
| Objective Field: | Expanding Knowledge in the Chemical Sciences |
| Author: | Canty, AJ (Professor Allan Canty) |
| Author: | Deverell, JA (Dr Jeremy Deverell) |
| Author: | Goemann, A (Dr Anissa Goemann) |
| Author: | Guijt, RM (Dr Rosanne Guijt) |
| Author: | Rodemann, T (Dr Thomas Rodemann) |
| Author: | Smith, Jason (Associate Professor Jason Smith) |
| ID Code: | 55156 |
| Year Published: | 2008 |
| Web of Science® Times Cited: | 13 |
| Deposited By: | Chemistry |
| Deposited On: | 2009-03-05 |
| Last Modified: | 2015-01-20 |
| Downloads: | 2 View Download Statistics |
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