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Kr (n=5-10,s,d,g) electronic wave packets: Electron time-of-flight resolution and the ac-Stark shift during wave-packet preparation
Citation
Gilb, S and Nestorov, V and Leone, SR and Keske, J and Nugent-Glandorf, L and Grant, ER, Kr (n=5-10,s,d,g) electronic wave packets: Electron time-of-flight resolution and the ac-Stark shift during wave-packet preparation, Physical Review A, 71, (4) pp. 1-8. ISSN 1050-2947 (2005) [Refereed Article]
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Copyright Statement
Copyright © 2005 The American Physical Society
Official URL: http://prola.aps.org/
DOI: doi:10.1103/PhysRevA.71.042709
Abstract
A two-color (3+1[prime]) pump-probe scheme is used to create Rydberg wave packets in krypton atoms. The ac-Stark shift, caused by the high intensity pump pulse, allows access to states with principal quantum numbers n=5–10 over a broad energy range. States shifted by as much as 3000 cm–1 during the pump pulse are coherently excited, resulting in wave-packet superpositions of field free states. By resolving the kinetic energy of the photoelectrons produced in the ionization probe step, numerous quantum beats are resolved and assigned. In addition, the energies of four previously unmeasured g states are determined.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Keywords: | krypton, Stark effect, spectral line shift, Rydberg states, atom-photon collisions, photoionisation, spectral line intensity, multiphoton processes, time of flight spectra |
| Research Division: | Chemical Sciences |
| Research Group: | Analytical Chemistry |
| Research Field: | Separation Science |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding Knowledge |
| Objective Field: | Expanding Knowledge in the Chemical Sciences |
| UTAS Author: | Keske, J (Dr John Keske) |
| ID Code: | 54435 |
| Year Published: | 2005 |
| Web of Science® Times Cited: | 3 |
| Deposited By: | Austn Centre for Research in Separation Science |
| Deposited On: | 2009-02-20 |
| Last Modified: | 2009-06-03 |
| Downloads: | 0 |
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