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Synthesis and solid-state structural characterisation of Pt(II,IV) bromide complexes containing bidentate organothiomethylpyridine heteroleptic ligands
Citation
Jones, RC and Skelton, BW and Tolhurst, V and White, AH and Wilson, AJ and Canty, AJ, Synthesis and solid-state structural characterisation of Pt(II,IV) bromide complexes containing bidentate organothiomethylpyridine heteroleptic ligands, Polyhedron, 26, (3) pp. 708-718. ISSN 0277-5387 (2007) [Refereed Article]
DOI: doi:10.1016/j.poly.2006.09.001
Abstract
A convenient synthetic method for the preparation of organothiomethylpyridine ligands 2-(RSCH2)C5H4N (R = Ph (L1), Me (L2)), 2-MeS-6-Me-C5H3N (L3), and 2-MeS-4-Me-C5H3N (L4) via the initial lithiation of substituted 2-picolines followed by the nucleophilic reaction with a diorganyldisulfide is described. The complexes [PtBr2L] (L = L1-L4) have been prepared in good to high yields as yellow solids with low solubility in organic solvents. The solid state structures of the complexes have been determined, showing the spatial arrangement of the complexes to depend significantly upon varying substituents within the ligand. The complexes undergo oxidation by bromine to form the tetravalent complexes [PtBr4(L)] (L = L1-L4). The solid state structures of [PtBr4(L2)] and [PtBr4(L4)] have been determined, and shown to be monomeric with the ligand chelating the platinum centre. © 2006 Elsevier Ltd. All rights reserved.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Other Chemical Sciences |
| Research Field: | Organometallic Chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding Knowledge |
| Objective Field: | Expanding Knowledge in the Chemical Sciences |
| UTAS Author: | Jones, RC (Dr Roderick Jones) |
| UTAS Author: | Tolhurst, V (Dr Vicki-Anne Gardiner) |
| UTAS Author: | Wilson, AJ (Mrs Amy Wilson) |
| UTAS Author: | Canty, AJ (Professor Allan Canty) |
| ID Code: | 50976 |
| Year Published: | 2007 |
| Web of Science® Times Cited: | 10 |
| Deposited By: | Chemistry |
| Deposited On: | 2007-08-01 |
| Last Modified: | 2009-12-10 |
| Downloads: | 0 |
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