eCite Digital Repository

Synthetic approaches to preparation of physiologically active polycyclic compounds. IV. X-Ray structural analysis of isomers of amino acid derivatives of adamantane

Citation

Zefirova, ON and Nurieva, EV and Chekhlov, AN and Aldoshin, SM and Nesterenko, PN and Zyk, NV and Zefirov, NS, Synthetic approaches to preparation of physiologically active polycyclic compounds. IV. X-Ray structural analysis of isomers of amino acid derivatives of adamantane, Russian Journal of Organic Chemistry, 40, (4) pp. 502-505. ISSN 1070-4280 (2004) [Refereed Article]

DOI: doi:10.1023/B:RUJO.0000036070.38148.e7

Abstract

According to the X-ray diffraction data, the major isomer of 1-(N-benzoyl-β-alanyloxy)-4-benzoyl-oxyadamantane obtained by esterification of β-alanine with 5-hydroxyadamantan-2-one and subsequent benzoylation has trans configuration. The trans-cis isomer ratio is 2:1. A similar isomer ratio was found for 1-(N-benzoylphenylisoseryloxy)-4- benzoyloxyadamantane synthesized by an analogous method.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Analytical Chemistry
Research Field:Separation Science
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Nesterenko, PN (Professor Pavel Nesterenko)
ID Code:47557
Year Published:2004
Web of Science® Times Cited:4
Deposited By:Chemistry
Deposited On:2007-09-18
Last Modified:2007-09-18
Downloads:0

Repository Staff Only: item control page