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Ion-exchange properties of hypercrosslinked polystyrene impregnated with methyl orange
Citation
Kiseleva, MG and Radchenko, LV and Nesterenko, PN, Ion-exchange properties of hypercrosslinked polystyrene impregnated with methyl orange, Journal of Chromatography A, 920, (1-2) pp. 79-85. ISSN 0021-9673 (2001) [Refereed Article]
DOI: doi:10.1016/S0021-9673(01)00696-3
Abstract
A novel bipolar stationary phase (HCPS-MO) was prepared by impregnation of hypercrosslinked polystyrene (HCPS) with methyl orange (MO; 4-dimethylamino-4′-sulfoazobenzene) and its ion-exchange properties were studied. Simultaneous separation of cations and anions on HCPS-MO is possible, although it behaves preferentially as a cation-exchanger. Unusual selectivity of HCPS-MO for alkali and alkaline-earth metal cations: Na+<Li+∼K+<Rb+<NH 4+<Cs+ and Mg2+<Sr2+<Ca2+<Ba2+ was observed. The effect of temperature on retention of alkali and alkaline-earth metal cations was studied. Separation of Na+, K+, Rb+, NH4+, Cs+, Mg2+ and Ca2+ on HCPS-MO with diluted cerium(III) nitrate solution as an eluent in single run is presented. © 2001 Elsevier Science B.V.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Analytical Chemistry |
| Research Field: | Separation Science |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding Knowledge |
| Objective Field: | Expanding Knowledge in the Chemical Sciences |
| UTAS Author: | Nesterenko, PN (Professor Pavel Nesterenko) |
| ID Code: | 47381 |
| Year Published: | 2001 |
| Web of Science® Times Cited: | 25 |
| Deposited By: | Chemistry |
| Deposited On: | 2007-09-14 |
| Last Modified: | 2011-10-24 |
| Downloads: | 0 |
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