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Ethylene Tri- and Tetramerization with Borate Cocatalysts: Effects on Activity, Selectivity, and Catalyst Degradation Pathways

Citation

McGuinness, DS and Overett, M and Tooze, RP and Blann, K and Dixon, JT and Slawin, AMZ, Ethylene Tri- and Tetramerization with Borate Cocatalysts: Effects on Activity, Selectivity, and Catalyst Degradation Pathways, Organometallics, 26, (4) pp. 1108-1111. ISSN 0276-7333 (2007) [Refereed Article]

DOI: doi:10.1021/om060906z

Abstract

Chromium-based ethylene tri- and tetramerization catalysts have been evaluated with a combination of trialkylaluminium and borate cocatalyst activation. A remarkable effect on activity and selectivity has been observed and studied, and a cocatalyst-induced degradation pathway has been identified. © 2007 American Chemical Society.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Other Chemical Sciences
Research Field:Industrial Chemistry
Objective Division:Manufacturing
Objective Group:Industrial Chemicals and Related Products
Objective Field:Organic Industrial Chemicals (excl. Resins, Rubber and Plastics)
Author:McGuinness, DS (Dr David McGuinness)
ID Code:46834
Year Published:2007
Web of Science® Times Cited:64
Deposited By:Chemistry
Deposited On:2007-08-01
Last Modified:2009-12-15
Downloads:0

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