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First Cr(III)-SNS Complexes and Their Use as Highly Efficient Catalysts for the Trimerization of Ethylene to 1-Hexene

journal contribution
posted on 2023-05-16, 19:50 authored by McGuinness, DS, Wasserscheid, P, Keim, W, Morgan, D, Dixon, JT, Bollmann, A, Maumela, H, Hess, F, Englert, U
Cr(III) complexes of tridentate SNS ligands have been prepared and evaluated as catalysts for ethylene trimerization, with several giving very high activity and excellent selectivity toward 1-hexene when activated with methylaluminoxane. The new complexes illustrate the potential of sulfur-based ligands on early transition metals for catalysis. Copyright © 2003 American Chemical Society.

History

Publication title

Journal of the American Chemical Society

Volume

125

Issue

18

Pagination

5272-5273

ISSN

0002-7863

Department/School

School of Natural Sciences

Publisher

American Chemical Society

Place of publication

Washington

Repository Status

  • Restricted

Socio-economic Objectives

Organic industrial chemicals (excl. resins, rubber and plastics)

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