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Reductive disproportionation of carbon dioxide by a Sm(II) complex: Unprecedented f-block element reactivity giving a carbonate complex

Citation

Davies, NW and Frey, A and Gardiner, MG and Wang, J, Reductive disproportionation of carbon dioxide by a Sm(II) complex: Unprecedented f-block element reactivity giving a carbonate complex, Chemical Communications, 2006, (46) pp. 4853-4855. ISSN 1359-7345 (2006) [Refereed Article]

DOI: doi:10.1039/b611784h

Abstract

A macrocyclic organosamarium(ii) complex has been shown to provide the first example of the reductive disproportionation of carbon dioxide, giving a bimetallic carbonate complex and carbon monoxide in a facile reaction under ambient conditions. © The Royal Society of Chemistry 2006.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Other Chemical Sciences
Research Field:Organometallic Chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Davies, NW (Associate Professor Noel Davies)
Author:Frey, A (Mr Alistair Frey)
Author:Gardiner, MG (Associate Professor Michael Gardiner)
Author:Wang, J (Dr Jun Wang)
ID Code:43109
Year Published:2006
Web of Science® Times Cited:54
Deposited By:Chemistry
Deposited On:2006-08-01
Last Modified:2012-03-05
Downloads:0

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