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Synthesis and Structures of the Ligands 1-Methylimidazol-2-yl(pyridin-2-yl)-methanone {(py)(mim)CO} and 1-Benzylimidazol-2-yl(1-phenylaldimine) (PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes [Mo(CO)4(L2-N,N')]

Citation

Batten, MP and Canty, AJ and Cavell, KJ and Skelton, BW and White, AH, Synthesis and Structures of the Ligands 1-Methylimidazol-2-yl(pyridin-2-yl)-methanone {(py)(mim)CO} and 1-Benzylimidazol-2-yl(1-phenylaldimine) (PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes [Mo(CO)4(L2-N,N')], Zeitschrift fuer Anorganische und Allgemeine Chemie, 632, (5) pp. 876-878. ISSN 0044-2313 (2006) [Refereed Article]

DOI: doi:10.1002/zaac.200500531

Abstract

The complexes [Mo(CO)4(L2-N.N′)] [L2 = 1-methylimidazol-2-yl(pyridin-2-yl)methanone and 1-benzylimidazol-2-yl(1- phenylaldimine)] have been synthesized from hexacarbonylmolybdenum(0) in order to define the coordination characteristics of the bidentate nitrogen-donor ligands; the complexes exhibit distorted octahedral coordination for molybdenum(0) and cis-bidentate ligand configurations. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Other Chemical Sciences
Research Field:Organometallic Chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Batten, MP (Mr Michael Batten)
Author:Canty, AJ (Professor Allan Canty)
Author:Cavell, KJ (Professor Kingsley Cavell)
ID Code:43085
Year Published:2006
Deposited By:Chemistry
Deposited On:2006-08-01
Last Modified:2008-01-03
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