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Synthesis and Structures of the Ligands 1-Methylimidazol-2-yl(pyridin-2-yl)-methanone {(py)(mim)CO} and 1-Benzylimidazol-2-yl(1-phenylaldimine) (PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes [Mo(CO)4(L2-N,N')]
Citation
Batten, MP and Canty, AJ and Cavell, KJ and Skelton, BW and White, AH, Synthesis and Structures of the Ligands 1-Methylimidazol-2-yl(pyridin-2-yl)-methanone {(py)(mim)CO} and 1-Benzylimidazol-2-yl(1-phenylaldimine) (PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes [Mo(CO)4(L2-N,N')], Zeitschrift fuer Anorganische und Allgemeine Chemie, 632, (5) pp. 876-878. ISSN 0044-2313 (2006) [Refereed Article]
DOI: doi:10.1002/zaac.200500531
Abstract
The complexes [Mo(CO)4(L2-N.N′)] [L2 = 1-methylimidazol-2-yl(pyridin-2-yl)methanone and 1-benzylimidazol-2-yl(1- phenylaldimine)] have been synthesized from hexacarbonylmolybdenum(0) in order to define the coordination characteristics of the bidentate nitrogen-donor ligands; the complexes exhibit distorted octahedral coordination for molybdenum(0) and cis-bidentate ligand configurations. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Inorganic chemistry |
| Research Field: | Organometallic chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding knowledge |
| Objective Field: | Expanding knowledge in the chemical sciences |
| UTAS Author: | Batten, MP (Mr Michael Batten) |
| UTAS Author: | Canty, AJ (Professor Allan Canty) |
| UTAS Author: | Cavell, KJ (Professor Kingsley Cavell) |
| ID Code: | 43085 |
| Year Published: | 2006 |
| Deposited By: | Chemistry |
| Deposited On: | 2006-08-01 |
| Last Modified: | 2008-01-03 |
| Downloads: | 0 |
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